L
Luis A. Oro
Researcher at University of Zaragoza
Publications - 764
Citations - 18487
Luis A. Oro is an academic researcher from University of Zaragoza. The author has contributed to research in topics: Catalysis & Rhodium. The author has an hindex of 57, co-authored 764 publications receiving 17692 citations. Previous affiliations of Luis A. Oro include Spanish National Research Council & Complutense University of Madrid.
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Journal ArticleDOI
Discrete Mixed-Valence Metal Chains: Iridium Pyridonate Blues.
Cristina Tejel,Miguel A. Ciriano,B. Eva Villarroya,Raquel Gelpi,José A. López,Fernando J. Lahoz,Luis A. Oro +6 more
TL;DR: In this article, it was shown that head-to-tail (HT) configurations are appropriate for building tetrametallic chains, contrary to previous speculations, and the isolated HT,HH tetrameric species are converted into the thermodynamically more stable HH,HH compounds.
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Thermally activated site exchange and quantum exchange coupling processes in unsymmetrical trihydride osmium compounds
Amaya Castillo,Guada Barea,Miguel A. Esteruelas,Fernando J. Lahoz,Agustí Lledós,Feliu Maseras,Javier Modrego,Enrique Oñate,Luis A. Oro,Natividad Ruiz,Eduardo Sola +10 more
TL;DR: In solution the hydride ligands of these complexes, which form two chemically equivalent unsymmetrical OsH(3) units, undergo two thermally activated site exchanges and show two different quantum exchange coupling processes.
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Synthesis, characterization and molecular structure of the hydroperoxo complex [(η5C5Me5)Ir(µ-pz)3Rh(OOH)(dppe)][BF4]; Hpz = pyrazole, dppe β 1,2-bis(diphenylphosphino)ethane
Daniel Carmona,M. Pilar Lamata,Joaquina Ferrer,Javier Modrego,Martin Perales,Fernando J. Lahoz,Reinaldo Atencio,Luis A. Oro +7 more
TL;DR: In this article, the synthesis and structural characterization of the title hydroperoxide complex is described, and a detailed description of the structure and properties of the complex is given. But the synthesis is not discussed.
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Mechanistic considerations on catalytic H/D exchange mediated by organometallic transition metal complexes
TL;DR: The metal-catalyzed H/D exchange is a multifaceted reaction whose mechanism depends strongly on the reaction conditions and on the metal complex used as a catalyst as mentioned in this paper.
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Alkene hydrogenation on an 11-vertex rhodathiaborane with full cluster participation.
TL;DR: In the proposed mechanism the classical hydrogen transfer from hydride metal complexes to olefins occurs twice: first upon coordination of the alkene to the rhodium centre in 2, and second concomitant with formation of a closo-hydridorhodathiaborane intermediate by migration of a BHB-bridging hydrogen atom to the metal.