M
Marc A. Hillmyer
Researcher at University of Minnesota
Publications - 598
Citations - 41267
Marc A. Hillmyer is an academic researcher from University of Minnesota. The author has contributed to research in topics: Copolymer & Polymerization. The author has an hindex of 103, co-authored 574 publications receiving 36643 citations. Previous affiliations of Marc A. Hillmyer include University of Colorado Boulder & University of North Carolina at Chapel Hill.
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Ultrafiltration membranes with a thin poly(styrene)-b-poly(isoprene) selective layer.
TL;DR: Ultrafiltration membranes with an 80 nm thick block polymer derived selective layer containing 20 nm cylindrical pores were prepared and were able to size-discriminate poly(ethylene oxide) (PEO) solutes in agreement with theoretical predictions.
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Influence of Conformational Asymmetry on Polymer−Polymer Interactions: An Entropic or Enthalpic Effect?
TL;DR: In this article, the authors show that conformational asymmetry leads to an enthalpic contribution to the Flory−Huggins parameter χ through an effective coordination number which is maximized when both of the blocks have large conformational symmetry paramete.
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An ordered nanoporous monolith from an elastomeric crosslinked block copolymer precursor
TL;DR: An ordered nanoporous monolith was prepared from a poly(isoprene-b-dimethylsiloxane) (PI-PDMS) hexagonally packed cylinder precursor.
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Catalytic decarbonylation of biomass-derived carboxylic acids as efficient route to commodity monomers
TL;DR: The palladium-catalyzed decarbonylation of bio-derived carboxylic acids to alkyl acrylates, styrene, and acrylonitrile is reported in this article.
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Nanopore and nanobushing arrays from ABC triblock thin films containing two etchable blocks
Shouwu Guo,Javid Rzayev,Travis S. Bailey,Andrew S. Zalusky,Roberto Olayo-Valles,Marc A. Hillmyer +5 more
TL;DR: In this article, the authors describe the preparation of polystyrene−polyisoprene-polylactide and polyisopreno-polystyrene −poly lactide ABC triblock terpolymer thin films followed by removal of one or both sacrificial components to give large area arrays of nanopores and more complex nanobushing structures, respectively.