M
Marc A. Hillmyer
Researcher at University of Minnesota
Publications - 598
Citations - 41267
Marc A. Hillmyer is an academic researcher from University of Minnesota. The author has contributed to research in topics: Copolymer & Polymerization. The author has an hindex of 103, co-authored 574 publications receiving 36643 citations. Previous affiliations of Marc A. Hillmyer include University of Colorado Boulder & University of North Carolina at Chapel Hill.
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Bulk Ring-Opening Transesterification Polymerization of the Renewable δ-Decalactone Using an Organocatalyst
TL;DR: The bulk ring-opening polymerization of renewable δ-decalactone using 1,5,7-triazabicyclo[4.0]dec-5-ene was carried out at temperatures between 7 and 110 °C as mentioned in this paper.
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Perpendicular orientation of cylindrical domains upon solvent annealing thin films of polystyrene-b-polylactide
Marylène Vayer,Marc A. Hillmyer,Mohammed Dirany,Guillaume Thevenin,R. Erre,Christophe Sinturel +5 more
TL;DR: In this article, a polystyrene-b-polylactide (PS-PLA) was employed as a precursor to nanoporous thin films containing perpendicular cylindrical channels.
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Sustainable Polyester Elastomers from Lactones: Synthesis, Properties, and Enzymatic Hydrolyzability
Guilhem X. De Hoe,Michael T. Zumstein,Brandon J. Tiegs,Jacob P. Brutman,Kristopher McNeill,Michael Sander,Geoffrey W. Coates,Marc A. Hillmyer +7 more
TL;DR: The synthesis of renewable, enzymatically hydrolyzable, and mechanically competitive polyester elastomers demonstrated high thermal stability and a low glass transition (-50 °C), indicating a wide range of use temperatures.
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Structural effects on the reprocessability and stress relaxation of crosslinked polyhydroxyurethanes
TL;DR: In this article, structural effects on reprocessability and stress relaxation in cross-linked polyhydroxyurethane (PHU) networks are studied, and it is shown that PHUs derived from bis(five-membered cyclic carbonates) are shown to decompose at temperatures needed for reprocessing, likely via initial reversion of the PHU linkage and subsequent side reactions of the liberated amine and cyclic carbate.
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Access to the Superstrong Segregation Regime with Nonionic ABC Copolymers
TL;DR: In this paper, the authors show that it is possible to access the superstrong segregation regime (SSSR) with nonionic, flexible coil block copolymers, by using three-monomer ABC triblock copolymer and judicious choice of chemical groups A, B, and C.