다중혈관 관상동맥 환자에서 y-문합을 이용하여 양쪽 내흉동맥만을 사용한 우회술의 조기 성적

[신간의 별자리x] 우리/미술, 그리고 ‘슬픔의 박물관’

The development of novel materials is a fundamental focal point of chemical research; and this interest is mandated by advancements in all areas of industry and technology. A good example of the synergism between scientific discovery and technological development is the electronics industry, where discoveries of new semiconducting materials resulted in the evolution from vacuum tubes to diodes and transistors, and eventually to miniature chips. The progression of this technology led to the development * To whom correspondence should be addressed. B.L.C.: (504) 2801385 (phone); (504) 280-3185 (fax); bcushing@uno.edu (e-mail). C.J.O.: (504)280-6846(phone);(504)280-3185(fax);coconnor@uno.edu (e-mail). 3893 Chem. Rev. 2004, 104, 3893−3946

http://depa.fquim.unam.mx/amyd//archivero/FidelmarLechugaSanabria_4940.pdf

Recent advances in the liquid-phase syntheses of inorganic nanoparticles.

The paper critically reviews the state of the art in the field of experimental techniques possible to be applied to the study of conductometric gas sensors based on semiconducting metal oxides. The used assessment criteria are subordinated to the proposed R&D approach, which focuses on the study, and subsequent modelling, of sensors’ performance in realistic operation conditions by means of a combination of phenomenological and spectroscopic techniques. With this viewpoint, the paper presents both the to-date achievements and shortcomings of different experimental techniques, describes – by using selected examples – how the proposed approach can be used and proposes a set of objectives for the near future.

Metal oxide-based gas sensor research: How to?

Solution-deposited metal oxides show great potential for large-area electronics, but they generally require high annealing temperatures, which are incompatible with flexible polymeric substrates. Combustion processing is now reported as a new low-temperature route for the deposition of diverse metal oxide films, and high-performance transistors are demonstrated using this method.

Low-temperature fabrication of high-performance metal oxide thin-film electronics via combustion processing

Silver and gold nanoparticles were synthesized by the sol-gel process in SiO 2 , TiO 2 , and ZrO 2 thin films. A versatile method, based on the use of coordination chemistry, is presented for stabilizing Ag + and Au 3+ ions in sol-gel systems. Various ligands of the metal ions were tested, and for each system it was possible to find a suitable ligand capable of stabilizing the metal ions and preventing gold precipitation onto the film surface. Thin films were prepared by spin-coating onto glass or fused silica substrates and then heat-treated at various temperatures in air or H 2 . atmosphere for nucleating the metal nanoparticles. The Ag particle size was about 10 nm after heating the SiO 2 film at 600°C and the TiO 2 and ZrO 2 films at 500°C. After heat treatment at 500°C, the Au particle size was 13 and 17 nm in the TiO 2 and ZrO 2 films, respectively. The films were characterized by UV-vis optical absorption spectroscopy and X-ray diffraction, for studying the nucleation and the growth of the metal nanoparticles. The results are discussed with regard to the embedding matrix, the temperature, and the atmosphere of the heat treatment, and it is concluded that crystallization of TiO 2 and ZrO 2 films may hinder the growth of Ag and Au particles.

Sol–Gel Synthesis and Characterization of Ag and Au Nanoparticles in SiO2, TiO2, and ZrO2 Thin Films

SnO2 nanocrystals were prepared by injecting a hydrolyzed methanol solution of SnCl4 into a tetradecene solution of dodecylamine. The resulting materials were annealed at 500 °C, providing 6−8 nm n...

The Role of Surface Oxygen Vacancies in the NO2 Sensing Properties of SnO2 Nanocrystals

Nanocrystalline SnO2, In2O3 and In2O3–SnO2 thin films have been prepared by modified sol–gel methods making use of no-standard precursors and a suitable surfactant. The oxide thin films have been used as gas-sensing layers in chemoresistive gas sensors and their performances in the detection of nitrogen dioxide (2–20 ppm in dry air) have been analysed by electrical characterization in controlled atmosphere. The samples have been structurally and morphologically characterized by X-ray diffraction and SEM, respectively. Good gas-sensing responses towards NO2 have been found for all the prepared samples with improved performances for the In2O3–SnO2 based sensor. The performances of the sensors have been discussed according to the surface chemical reactions between the gas phase and the semiconductor.

Nanostructured In2O3-SnO2 sol-gel thin film as material for NO2 detection

This communication reports the formation of the high-pressure modification of indium (III) oxide (so-called corundum-type or hexagonal In2O3) under ambient pressure. Corundum-type In2O3 was obtained by precipitation from the solution of indium nitrate in methanol by adding concentrated ammonia solution and subsequent calcination of the obtained precipitate at 250-500 degrees C. The role of the impurities and the additives in the stabilization of corundum-type In2O3 is discussed.

Ambient pressure synthesis of corundum-type IN2O3.

This paper reports the use of a semiconductor thin films based electronic nose to recognise the rancidity of two different kinds of milk (UHT and pasteurised) during their ageing days The employed sensor array consists of five different SnO 2 thin films prepared by means of the sol–gel technology The data coming from the response of the sensors have been elaborated by principal component analysis (PCA) in order to obtain a classification of the data clusters related to different milk ageing days and so track the dynamic evolution of milk rancidity The obtained results could lead to industrial applications in dairying for the quality control of starting milk and the rancidity check during the different stages of production

Mauro Epifani

Papers

Sol–Gel Synthesis and Characterization of Ag and Au Nanoparticles in SiO2, TiO2, and ZrO2 Thin Films

The Role of Surface Oxygen Vacancies in the NO2 Sensing Properties of SnO2 Nanocrystals

Nanostructured In2O3-SnO2 sol-gel thin film as material for NO2 detection

Ambient pressure synthesis of corundum-type IN2O3.

Monitoring of rancidity of milk by means of an electronic nose and a dynamic PCA analysis