Although gold is the subject of one of the most ancient themes of investigation in science, its renaissance now leads to an exponentially increasing number of publications, especially in the context of emerging nanoscience and nanotechnology with nanoparticles and self-assembled monolayers (SAMs). We will limit the present review to gold nanoparticles (AuNPs), also called gold colloids. AuNPs are the most stable metal nanoparticles, and they present fascinating aspects such as their assembly of multiple types involving materials science, the behavior of the individual particles, size-related electronic, magnetic and optical properties (quantum size effect), and their applications to catalysis and biology. Their promises are in these fields as well as in the bottom-up approach of nanotechnology, and they will be key materials and building block in the 21st century. Whereas the extraction of gold started in the 5th millennium B.C. near Varna (Bulgaria) and reached 10 tons per year in Egypt around 1200-1300 B.C. when the marvelous statue of Touthankamon was constructed, it is probable that “soluble” gold appeared around the 5th or 4th century B.C. in Egypt and China. In antiquity, materials were used in an ecological sense for both aesthetic and curative purposes. Colloidal gold was used to make ruby glass 293 Chem. Rev. 2004, 104, 293−346

Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology.

Titanium Dioxide Nanomaterials: Synthesis, Properties, Modifications, and Applications

Dye-sensitized solar cells (DSCs) offer the possibilities to design solar cells with a large flexibility in shape, color, and transparency. DSC research groups have been established around the worl ...

/pdf/dye-sensitized-solar-cells-50b0w2bhsr.pdf

Dye-Sensitized Solar Cells

J. Appl. Cryst.の発刊に際して

The long-standing challenge of designing and constructing new crystalline solid-state materials from molecular building blocks is just beginning to be addressed with success. A conceptual approach that requires the use of secondary building units to direct the assembly of ordered frameworks epitomizes this process: we call this approach reticular synthesis. This chemistry has yielded materials designed to have predetermined structures, compositions and properties. In particular, highly porous frameworks held together by strong metal-oxygen-carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.

/pdf/reticular-synthesis-and-the-design-of-new-materials-lazbx7tdux.pdf

Reticular synthesis and the design of new materials

In nanocrystalline dye-sensitized solar cells (DSSCs) the absorption of a large fraction of the incident solar radiation is important for achieving high efficiencies. We develop a model to include both the optical process and the electrochemical process. This model allows us to calculate the performance of the different optical designs (for example the different scattering layers and the different reflecting plane). It is found that appropriate optical designs can improve the performance of DSSCs greatly.

Optical Design of Dye-Sensitized Nanocrystalline Solar Cells

A 53-year-old male presented with a dissecting aneurysm of the extracranial distal internal carotid artery (ICA) treated by aneurysm removal with interposition of a saphenous vein graft. The surgical approach involved sectioning of Riolan's nosegay.

Surgical treatment of extracranial distal internal carotid artery dissecting aneurysm--case report.

PROBLEM TO BE SOLVED: To provide a high intensifying effect for Raman scattering, to make uniformity and reproducibility excellent, and to allow very simple and inexpensive production. SOLUTION: This Raman scattering measuring sensor concerned in the present invention is provided with particle layers arrayed periodically with a plurality of particles having the same shape and the same size coated with metal on each surface thereof, to have a clearance into which a substance to measure Raman scattering is able to enter at least among the respective particles and to form periodical uneven parts on a surface of the particle layer, on a substrate. COPYRIGHT: (C)2004,JPO

Raman scattering measuring sensor, and its manufacturing method

Five cases of the supratentorial extradural hematomas secondary to the posterior fossa craniectomy were reported. The site of the hematoma was far from the operative field and two cases showed acute course and three were rather mild. The symptoms of this complication were the unsuspected sensorium disturbance, anisocoria and the non-functioning ventricular drainage. Two cases died of this complication and two were severely disabled. The mechanism of this complication is not clearly understood. The lowering of the ventricular pressure by the ventricular tap during the operation may play significant role in the formation of the extradural hematoma. The younger age of the cases and the long history of increased intracranial pressure were stressed in the literature. The significance of the management of the ventricular pressure during the operation was emphasized. The prevention is the best treatment.

[Supratentorial extradural hematomas following posterior fossa craniectomy (author's transl)].

A method for treating severe heart failure, comprising administering to a patient an effective amount of a benzazepine compound (1): wherein R1 is H or halogen, R2 is OH, or -NR5R6 (R5 and R6 are H or lower alkyl, R3 is H, halogen, lower alkyl, or lower alkoxy, R4 is halogen, lower alkyl or lower alkoxy, or a salt thereof, and a pharmaceutical composition containing the benzazepine compound (1) or a salt thereof and use of the compound (1) or a salt thereof for preparing a medicament for treatment of severe heart failure.

Osamu Sato

Papers

Optical Design of Dye-Sensitized Nanocrystalline Solar Cells

Surgical treatment of extracranial distal internal carotid artery dissecting aneurysm--case report.

Raman scattering measuring sensor, and its manufacturing method

[Supratentorial extradural hematomas following posterior fossa craniectomy (author's transl)].

Method for treating severe heart failure and medicament therefor