This article reviews the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations. The Dirac electrons can be controlled by application of external electric and magnetic fields, or by altering sample geometry and/or topology. The Dirac electrons behave in unusual ways in tunneling, confinement, and the integer quantum Hall effect. The electronic properties of graphene stacks are discussed and vary with stacking order and number of layers. Edge (surface) states in graphene depend on the edge termination (zigzag or armchair) and affect the physical properties of nanoribbons. Different types of disorder modify the Dirac equation leading to unusual spectroscopic and transport properties. The effects of electron-electron and electron-phonon interactions in single layer and multilayer graphene are also presented.

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The electronic properties of graphene

Deposits of clastic carbonate-dominated (calciclastic) sedimentary slope systems in the rock record have been identified mostly as linearly-consistent carbonate apron deposits, even though most ancient clastic carbonate slope deposits fit the submarine fan systems better. Calciclastic submarine fans are consequently rarely described and are poorly understood. Subsequently, very little is known especially in mud-dominated calciclastic submarine fan systems. Presented in this study are a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) that reveals a >250 m thick calciturbidite complex deposited in a calciclastic submarine fan setting. Seven facies are recognised from core and thin section characterisation and are grouped into three carbonate turbidite sequences. They include: 1) Calciturbidites, comprising mostly of highto low-density, wavy-laminated bioclast-rich facies; 2) low-density densite mudstones which are characterised by planar laminated and unlaminated muddominated facies; and 3) Calcidebrites which are muddy or hyper-concentrated debrisflow deposits occurring as poorly-sorted, chaotic, mud-supported floatstones. These

Phd by thesis

It is possible to say that zeolites are the most widely used catalysts in industry They are crystalline microporous materials which have become extremely successful as catalysts for oil refining, petrochemistry, and organic synthesis in the production of fine and speciality chemicals, particularly when dealing with molecules having kinetic diameters below 10 A The reason for their success in catalysis is related to the following specific features of these materials:1 (1) They have very high surface area and adsorption capacity (2) The adsorption properties of the zeolites can be controlled, and they can be varied from hydrophobic to hydrophilic type materials (3) Active sites, such as acid sites for instance, can be generated in the framework and their strength and concentration can be tailored for a particular application (4) The sizes of their channels and cavities are in the range typical for many molecules of interest (5-12 A), and the strong electric fields2 existing in those micropores together with an electronic confinement of the guest molecules3 are responsible for a preactivation of the reactants (5) Their intricate channel structure allows the zeolites to present different types of shape selectivity, ie, product, reactant, and transition state, which can be used to direct a given catalytic reaction toward the desired product avoiding undesired side reactions (6) All of these properties of zeolites, which are of paramount importance in catalysis and make them attractive choices for the types of processes listed above, are ultimately dependent on the thermal and hydrothermal stability of these materials In the case of zeolites, they can be activated to produce very stable materials not just resistant to heat and steam but also to chemical attacks Avelino Corma Canos was born in Moncofar, Spain, in 1951 He studied chemistry at the Universidad de Valencia (1967−1973) and received his PhD at the Universidad Complutense de Madrid in 1976 He became director of the Instituto de Tecnologia Quimica (UPV-CSIC) at the Universidad Politecnica de Valencia in 1990 His current research field is zeolites as catalysts, covering aspects of synthesis, characterization and reactivity in acid−base and redox catalysis A Corma has written about 250 articles on these subjects in international journals, three books, and a number of reviews and book chapters He is a member of the Editorial Board of Zeolites, Catalysis Review Science and Engineering, Catalysis Letters, Applied Catalysis, Journal of Molecular Catalysis, Research Trends, CaTTech, and Journal of the Chemical Society, Chemical Communications A Corma is coauthor of 20 patents, five of them being for commercial applications He has been awarded with the Dupont Award on new materials (1995), and the Spanish National Award “Leonardo Torres Quevedo” on Technology Research (1996) 2373 Chem Rev 1997, 97, 2373−2419

From Microporous to Mesoporous Molecular-Sieve Materials and Their Use in Catalysis

Graphene — a recently isolated one-atom-thick layered form of graphite — is a hot topic in the materials science and condensed matter physics communities, where it is proving to be a popular model system for investigation. An experiment involving individual graphene sheets suspended over a microscale scaffold has allowed structure determination using transmission electron microscopy and diffraction, perhaps paving the way towards an answer to the question of why graphene can exist at all. The 'two-dimensional' sheets, it seems, are not flat, but wavy. The undulations are less pronounced in a two-layer system, and disappear in multilayer samples. Learning more about this 'waviness' may reveal what makes these extremely thin carbon membranes so stable. Investigations of individual graphene sheets freely suspended on a microfabricated scaffold in vacuum or in air reveal that the membranes are not perfectly flat, but exhibit an intrinsic waviness, such that the surface normal varies by several degrees, and out-of-plane deformations reach 1 nm. The recent discovery of graphene has sparked much interest, thus far focused on the peculiar electronic structure of this material, in which charge carriers mimic massless relativistic particles1,2,3. However, the physical structure of graphene—a single layer of carbon atoms densely packed in a honeycomb crystal lattice—is also puzzling. On the one hand, graphene appears to be a strictly two-dimensional material, exhibiting such a high crystal quality that electrons can travel submicrometre distances without scattering. On the other hand, perfect two-dimensional crystals cannot exist in the free state, according to both theory and experiment4,5,6,7,8,9. This incompatibility can be avoided by arguing that all the graphene structures studied so far were an integral part of larger three-dimensional structures, either supported by a bulk substrate or embedded in a three-dimensional matrix1,2,3,9,10,11,12. Here we report on individual graphene sheets freely suspended on a microfabricated scaffold in vacuum or air. These membranes are only one atom thick, yet they still display long-range crystalline order. However, our studies by transmission electron microscopy also reveal that these suspended graphene sheets are not perfectly flat: they exhibit intrinsic microscopic roughening such that the surface normal varies by several degrees and out-of-plane deformations reach 1 nm. The atomically thin single-crystal membranes offer ample scope for fundamental research and new technologies, whereas the observed corrugations in the third dimension may provide subtle reasons for the stability of two-dimensional crystals13,14,15.

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The structure of suspended graphene sheets

N G van Kampen 1981 Amsterdam: North-Holland xiv + 419 pp price Dfl 180 This is a book which, at a lower price, could be expected to become an essential part of the library of every physical scientist concerned with problems involving fluctuations and stochastic processes, as well as those who just enjoy a beautifully written book. It provides an extensive graduate-level introduction which is clear, cautious, interesting and readable.

https://iopscience.iop.org/article/10.1088/0031-9112/34/4/040/pdf

Stochastic Processes in Physics and Chemistry

The functional renormalization group for the random-field and random-anisotropy O(N) sigma models is studied to 2 loop. The ferromagnetic-disordered (F-D) transition fixed point is found to next order in d = 4 + epsilon for N > N(c) (N(c) = 2.834 740 8 for random field, N(c) = 9.441 21 for random anisotropy). For N < N(c) the lower critical dimension d = d(lc) plunges below d(lc) = 4: we find two fixed points, one describing the quasiordered phase, the other is novel and describes the F-D transition. d(lc) can be obtained in an (N(c)-N) expansion. The theory is also analyzed at large N and a glassy regime is found.

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Random-field spin models beyond 1 loop: a mechanism for decreasing the lower critical dimension.

An overview is given of the new theories and experiments on the phase diagram of type II superconductors, which in recent years have progressed from the Abrikosov mean field theory to the "vortex matter" picture. We then detail some theoretical tools which allow to describe the melting of the vortex lattice, the collective pinning and creep theory, and the Bragg glass theory. It is followed by a short presentation of other glass phases of vortices, as well as phases of moving vortices.

Novel phases of vortices in superconductors

We introduce a method, based on an exact calculation of the effective action at large N, to bridge the gap between mean-field theory and renormalization in complex systems. We apply it to a d-dimensional manifold in a random potential for large embedding space dimension N. This yields a functional renormalization group equation valid for any d, which contains both the O(epsilon=4-d) results of Balents-Fisher and some of the nontrivial results of the Mezard-Parisi solution, thus shedding light on both. Corrections are computed at order O(1/N). Applications to the Kardar-Parisi-Zhang growth model, random field, and mode coupling in glasses are mentioned.

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Functional renormalization group at large N for disordered systems.

The ground-state properties of N spinless free fermions in a d-dimensional confining potential are studied. We find that any n-point correlation function has a simple determinantal structure that allows us to compute several properties exactly for large N. We show that the average density has a finite support with an edge, and near this edge the density exhibits a universal (valid for a wide class of potentials) scaling behavior for large N. The associated edge scaling function is computed exactly and generalizes to any d the edge electron gas result of Kohn and Mattsson in d = 3 (Kohn W. and Mattsson A. E., Phys. Rev. Lett., 81 (1998) 3487). In addition, we calculate the kernel (that characterizes any n-point correlation function) for large N and show that, when appropriately scaled, it depends only on dimension d, but has otherwise universal scaling forms, at the edges. The edge kernel, for higher d, generalizes the Airy kernel in one dimension, well known from the random matrix theory.

https://hal.archives-ouvertes.fr/hal-01250783/document

Universal ground-state properties of free fermions in a d-dimensional trap

The dynamics of a glass transition is discussed in terms of the motion of a particle in a one-dimensional correlated random potential. An exact calculation of the velocity V under an applied force jr demonstrates a variety of dynamic regimes depending on the range of correlations. In a gaussian potential with correlator C(x) = x ~, we find a transition from ohmic behavior (), < 0) to creep motion V ~ exp(- const/f ~) (0 < "y < 1). This provides a generic picture of the glass transition in systems where long-range correlations in the effective disorder develop due to elasticity such as elastic manifolds subject to quenched disorder and the vortex-glass transition in superconductors.

Pierre Le Doussal

Papers

Random-field spin models beyond 1 loop: a mechanism for decreasing the lower critical dimension.

Novel phases of vortices in superconductors

Functional renormalization group at large N for disordered systems.

Universal ground-state properties of free fermions in a d-dimensional trap

Creep in one dimension and phenomenological theory of glass dynamics