This article reviews the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations. The Dirac electrons can be controlled by application of external electric and magnetic fields, or by altering sample geometry and/or topology. The Dirac electrons behave in unusual ways in tunneling, confinement, and the integer quantum Hall effect. The electronic properties of graphene stacks are discussed and vary with stacking order and number of layers. Edge (surface) states in graphene depend on the edge termination (zigzag or armchair) and affect the physical properties of nanoribbons. Different types of disorder modify the Dirac equation leading to unusual spectroscopic and transport properties. The effects of electron-electron and electron-phonon interactions in single layer and multilayer graphene are also presented.

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The electronic properties of graphene

Deposits of clastic carbonate-dominated (calciclastic) sedimentary slope systems in the rock record have been identified mostly as linearly-consistent carbonate apron deposits, even though most ancient clastic carbonate slope deposits fit the submarine fan systems better. Calciclastic submarine fans are consequently rarely described and are poorly understood. Subsequently, very little is known especially in mud-dominated calciclastic submarine fan systems. Presented in this study are a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) that reveals a >250 m thick calciturbidite complex deposited in a calciclastic submarine fan setting. Seven facies are recognised from core and thin section characterisation and are grouped into three carbonate turbidite sequences. They include: 1) Calciturbidites, comprising mostly of highto low-density, wavy-laminated bioclast-rich facies; 2) low-density densite mudstones which are characterised by planar laminated and unlaminated muddominated facies; and 3) Calcidebrites which are muddy or hyper-concentrated debrisflow deposits occurring as poorly-sorted, chaotic, mud-supported floatstones. These

Phd by thesis

It is possible to say that zeolites are the most widely used catalysts in industry They are crystalline microporous materials which have become extremely successful as catalysts for oil refining, petrochemistry, and organic synthesis in the production of fine and speciality chemicals, particularly when dealing with molecules having kinetic diameters below 10 A The reason for their success in catalysis is related to the following specific features of these materials:1 (1) They have very high surface area and adsorption capacity (2) The adsorption properties of the zeolites can be controlled, and they can be varied from hydrophobic to hydrophilic type materials (3) Active sites, such as acid sites for instance, can be generated in the framework and their strength and concentration can be tailored for a particular application (4) The sizes of their channels and cavities are in the range typical for many molecules of interest (5-12 A), and the strong electric fields2 existing in those micropores together with an electronic confinement of the guest molecules3 are responsible for a preactivation of the reactants (5) Their intricate channel structure allows the zeolites to present different types of shape selectivity, ie, product, reactant, and transition state, which can be used to direct a given catalytic reaction toward the desired product avoiding undesired side reactions (6) All of these properties of zeolites, which are of paramount importance in catalysis and make them attractive choices for the types of processes listed above, are ultimately dependent on the thermal and hydrothermal stability of these materials In the case of zeolites, they can be activated to produce very stable materials not just resistant to heat and steam but also to chemical attacks Avelino Corma Canos was born in Moncofar, Spain, in 1951 He studied chemistry at the Universidad de Valencia (1967−1973) and received his PhD at the Universidad Complutense de Madrid in 1976 He became director of the Instituto de Tecnologia Quimica (UPV-CSIC) at the Universidad Politecnica de Valencia in 1990 His current research field is zeolites as catalysts, covering aspects of synthesis, characterization and reactivity in acid−base and redox catalysis A Corma has written about 250 articles on these subjects in international journals, three books, and a number of reviews and book chapters He is a member of the Editorial Board of Zeolites, Catalysis Review Science and Engineering, Catalysis Letters, Applied Catalysis, Journal of Molecular Catalysis, Research Trends, CaTTech, and Journal of the Chemical Society, Chemical Communications A Corma is coauthor of 20 patents, five of them being for commercial applications He has been awarded with the Dupont Award on new materials (1995), and the Spanish National Award “Leonardo Torres Quevedo” on Technology Research (1996) 2373 Chem Rev 1997, 97, 2373−2419

From Microporous to Mesoporous Molecular-Sieve Materials and Their Use in Catalysis

Graphene — a recently isolated one-atom-thick layered form of graphite — is a hot topic in the materials science and condensed matter physics communities, where it is proving to be a popular model system for investigation. An experiment involving individual graphene sheets suspended over a microscale scaffold has allowed structure determination using transmission electron microscopy and diffraction, perhaps paving the way towards an answer to the question of why graphene can exist at all. The 'two-dimensional' sheets, it seems, are not flat, but wavy. The undulations are less pronounced in a two-layer system, and disappear in multilayer samples. Learning more about this 'waviness' may reveal what makes these extremely thin carbon membranes so stable. Investigations of individual graphene sheets freely suspended on a microfabricated scaffold in vacuum or in air reveal that the membranes are not perfectly flat, but exhibit an intrinsic waviness, such that the surface normal varies by several degrees, and out-of-plane deformations reach 1 nm. The recent discovery of graphene has sparked much interest, thus far focused on the peculiar electronic structure of this material, in which charge carriers mimic massless relativistic particles1,2,3. However, the physical structure of graphene—a single layer of carbon atoms densely packed in a honeycomb crystal lattice—is also puzzling. On the one hand, graphene appears to be a strictly two-dimensional material, exhibiting such a high crystal quality that electrons can travel submicrometre distances without scattering. On the other hand, perfect two-dimensional crystals cannot exist in the free state, according to both theory and experiment4,5,6,7,8,9. This incompatibility can be avoided by arguing that all the graphene structures studied so far were an integral part of larger three-dimensional structures, either supported by a bulk substrate or embedded in a three-dimensional matrix1,2,3,9,10,11,12. Here we report on individual graphene sheets freely suspended on a microfabricated scaffold in vacuum or air. These membranes are only one atom thick, yet they still display long-range crystalline order. However, our studies by transmission electron microscopy also reveal that these suspended graphene sheets are not perfectly flat: they exhibit intrinsic microscopic roughening such that the surface normal varies by several degrees and out-of-plane deformations reach 1 nm. The atomically thin single-crystal membranes offer ample scope for fundamental research and new technologies, whereas the observed corrugations in the third dimension may provide subtle reasons for the stability of two-dimensional crystals13,14,15.

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The structure of suspended graphene sheets

N G van Kampen 1981 Amsterdam: North-Holland xiv + 419 pp price Dfl 180 This is a book which, at a lower price, could be expected to become an essential part of the library of every physical scientist concerned with problems involving fluctuations and stochastic processes, as well as those who just enjoy a beautifully written book. It provides an extensive graduate-level introduction which is clear, cautious, interesting and readable.

https://iopscience.iop.org/article/10.1088/0031-9112/34/4/040/pdf

Stochastic Processes in Physics and Chemistry

We study the motion of an elastic object driven in a disordered environment in presence of both dissipation and inertia. We consider random forces with the statistics of random walks and reduce the problem to a single degree of freedom. It is the extension of the mean-field Alessandro-Beatrice- Bertotti-Montorsi (ABBM) model in presence of an inertial mass m. While the ABBM model can be solved exactly, its extension to inertia exhibits complicated history dependence due to oscillations and backward motion. The characteristic scales for avalanche motion are studied from numerics and qualitative arguments. To make analytical progress, we consider two variants which coincide with the original model whenever the particle moves only forward. Using a combination of analytical and numerical methods together with simulations, we characterize the distributions of instantaneous acceleration and velocity, and compare them in these three models. We show that for large driving velocity, all three models share the same large-deviation function for positive velocities, which is obtained analytically for small and large m, as well as for m=6/25. The effect of small additional thermal and quantum fluctuations can be treated within an approximate method.

http://www.phys.ens.fr/~wiese/pdf/PhysRevE.85.061116.pdf

Distribution of velocities and acceleration for a particle in Brownian correlated disorder: inertial case.

We consider the number N_{θ_{A}}(θ) of eigenvalues e^{iθ_{j}} of a random unitary matrix, drawn from CUE_{β}(N), in the interval θ_{j}∈[θ_{A},θ]. The deviations from its mean, N_{θ_{A}}(θ)-E[N_{θ_{A}}(θ)], form a random process as function of θ. We study the maximum of this process, by exploiting the mapping onto the statistical mechanics of log-correlated random landscapes. By using an extended Fisher-Hartwig conjecture supplemented with the freezing duality conjecture for log-correlated fields, we obtain the cumulants of the distribution of that maximum for any β>0. It exhibits combined features of standard counting statistics of fermions (free for β=2 and with Sutherland-type interaction for β≠2) in an interval and extremal statistics of the fractional Brownian motion with Hurst index H=0. The β=2 results are expected to apply to the statistics of zeroes of the Riemann Zeta function.

Statistics of Extremes in Eigenvalue-Counting Staircases.

Translational order and neutron diffraction studies of magnetic flux lattices.

We study the atypically large deviations of the height $H \sim {\cal O}(t)$ at the origin at late times in $1+1$-dimensional growth models belonging to the Kardar-Parisi-Zhang (KPZ) universality class. We present exact results for the rate functions for the discrete single step growth model, as well as for the continuum KPZ equation in a droplet geometry. Based on our exact calculation of the rate functions we argue that models in the KPZ class undergo a third order phase transition from a strong coupling to a weak coupling phase, at late times.

Large deviations for the height in 1D Kardar-Parisi-Zhang growth at late times

We study a model of two layers, each consisting of a $d$-dimensional elastic object driven over a random substrate, and mutually interacting through a viscous coupling. For this model, the mean-field theory (i.e., a fully connected model) predicts a transition from elastic depinning to hysteretic plastic depinning as disorder or viscous coupling is increased. A functional renormalization group analysis shows that any small interlayer viscous coupling destabilizes the standard (decoupled) elastic depinning functional renormalization group fixed point for $d\ensuremath{\le}4$, while for $dg4$ most aspects of the mean-field theory are recovered. A one-loop study at nonzero velocity indicates, for $dl4$, coexistence of a moving state and a pinned state below the elastic depinning threshold, with hysteretic plastic depinning for periodic and nonperiodic driven layers. A two-loop analysis of quasistatics unveils the possibility of more subtle effects, including a new universality class for nonperiodic objects. We also study the model in $d=0$, i.e., two coupled particles, and show that hysteresis does not always exist as the periodic steady state with coupled layers can be dynamically unstable. It is also proved that stable pinned configurations remain dynamically stable in presence of a viscous coupling in any dimension $d$. Moreover, the layer model for periodic objects is stable to an infinitesimal commensurate density coupling. Our work shows that a careful study of attractors in phase space and their basin of attraction is necessary to obtain a firm conclusion for dimensions $d=1,2,3$.

/pdf/depinning-in-a-two-layer-model-of-plastic-flow-2mvzir1uck.pdf

Pierre Le Doussal

Papers

Distribution of velocities and acceleration for a particle in Brownian correlated disorder: inertial case.

Statistics of Extremes in Eigenvalue-Counting Staircases.

Translational order and neutron diffraction studies of magnetic flux lattices.

Large deviations for the height in 1D Kardar-Parisi-Zhang growth at late times

Depinning in a two-layer model of plastic flow