This article reviews the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations. The Dirac electrons can be controlled by application of external electric and magnetic fields, or by altering sample geometry and/or topology. The Dirac electrons behave in unusual ways in tunneling, confinement, and the integer quantum Hall effect. The electronic properties of graphene stacks are discussed and vary with stacking order and number of layers. Edge (surface) states in graphene depend on the edge termination (zigzag or armchair) and affect the physical properties of nanoribbons. Different types of disorder modify the Dirac equation leading to unusual spectroscopic and transport properties. The effects of electron-electron and electron-phonon interactions in single layer and multilayer graphene are also presented.

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The electronic properties of graphene

Deposits of clastic carbonate-dominated (calciclastic) sedimentary slope systems in the rock record have been identified mostly as linearly-consistent carbonate apron deposits, even though most ancient clastic carbonate slope deposits fit the submarine fan systems better. Calciclastic submarine fans are consequently rarely described and are poorly understood. Subsequently, very little is known especially in mud-dominated calciclastic submarine fan systems. Presented in this study are a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) that reveals a >250 m thick calciturbidite complex deposited in a calciclastic submarine fan setting. Seven facies are recognised from core and thin section characterisation and are grouped into three carbonate turbidite sequences. They include: 1) Calciturbidites, comprising mostly of highto low-density, wavy-laminated bioclast-rich facies; 2) low-density densite mudstones which are characterised by planar laminated and unlaminated muddominated facies; and 3) Calcidebrites which are muddy or hyper-concentrated debrisflow deposits occurring as poorly-sorted, chaotic, mud-supported floatstones. These

Phd by thesis

It is possible to say that zeolites are the most widely used catalysts in industry They are crystalline microporous materials which have become extremely successful as catalysts for oil refining, petrochemistry, and organic synthesis in the production of fine and speciality chemicals, particularly when dealing with molecules having kinetic diameters below 10 A The reason for their success in catalysis is related to the following specific features of these materials:1 (1) They have very high surface area and adsorption capacity (2) The adsorption properties of the zeolites can be controlled, and they can be varied from hydrophobic to hydrophilic type materials (3) Active sites, such as acid sites for instance, can be generated in the framework and their strength and concentration can be tailored for a particular application (4) The sizes of their channels and cavities are in the range typical for many molecules of interest (5-12 A), and the strong electric fields2 existing in those micropores together with an electronic confinement of the guest molecules3 are responsible for a preactivation of the reactants (5) Their intricate channel structure allows the zeolites to present different types of shape selectivity, ie, product, reactant, and transition state, which can be used to direct a given catalytic reaction toward the desired product avoiding undesired side reactions (6) All of these properties of zeolites, which are of paramount importance in catalysis and make them attractive choices for the types of processes listed above, are ultimately dependent on the thermal and hydrothermal stability of these materials In the case of zeolites, they can be activated to produce very stable materials not just resistant to heat and steam but also to chemical attacks Avelino Corma Canos was born in Moncofar, Spain, in 1951 He studied chemistry at the Universidad de Valencia (1967−1973) and received his PhD at the Universidad Complutense de Madrid in 1976 He became director of the Instituto de Tecnologia Quimica (UPV-CSIC) at the Universidad Politecnica de Valencia in 1990 His current research field is zeolites as catalysts, covering aspects of synthesis, characterization and reactivity in acid−base and redox catalysis A Corma has written about 250 articles on these subjects in international journals, three books, and a number of reviews and book chapters He is a member of the Editorial Board of Zeolites, Catalysis Review Science and Engineering, Catalysis Letters, Applied Catalysis, Journal of Molecular Catalysis, Research Trends, CaTTech, and Journal of the Chemical Society, Chemical Communications A Corma is coauthor of 20 patents, five of them being for commercial applications He has been awarded with the Dupont Award on new materials (1995), and the Spanish National Award “Leonardo Torres Quevedo” on Technology Research (1996) 2373 Chem Rev 1997, 97, 2373−2419

From Microporous to Mesoporous Molecular-Sieve Materials and Their Use in Catalysis

Graphene — a recently isolated one-atom-thick layered form of graphite — is a hot topic in the materials science and condensed matter physics communities, where it is proving to be a popular model system for investigation. An experiment involving individual graphene sheets suspended over a microscale scaffold has allowed structure determination using transmission electron microscopy and diffraction, perhaps paving the way towards an answer to the question of why graphene can exist at all. The 'two-dimensional' sheets, it seems, are not flat, but wavy. The undulations are less pronounced in a two-layer system, and disappear in multilayer samples. Learning more about this 'waviness' may reveal what makes these extremely thin carbon membranes so stable. Investigations of individual graphene sheets freely suspended on a microfabricated scaffold in vacuum or in air reveal that the membranes are not perfectly flat, but exhibit an intrinsic waviness, such that the surface normal varies by several degrees, and out-of-plane deformations reach 1 nm. The recent discovery of graphene has sparked much interest, thus far focused on the peculiar electronic structure of this material, in which charge carriers mimic massless relativistic particles1,2,3. However, the physical structure of graphene—a single layer of carbon atoms densely packed in a honeycomb crystal lattice—is also puzzling. On the one hand, graphene appears to be a strictly two-dimensional material, exhibiting such a high crystal quality that electrons can travel submicrometre distances without scattering. On the other hand, perfect two-dimensional crystals cannot exist in the free state, according to both theory and experiment4,5,6,7,8,9. This incompatibility can be avoided by arguing that all the graphene structures studied so far were an integral part of larger three-dimensional structures, either supported by a bulk substrate or embedded in a three-dimensional matrix1,2,3,9,10,11,12. Here we report on individual graphene sheets freely suspended on a microfabricated scaffold in vacuum or air. These membranes are only one atom thick, yet they still display long-range crystalline order. However, our studies by transmission electron microscopy also reveal that these suspended graphene sheets are not perfectly flat: they exhibit intrinsic microscopic roughening such that the surface normal varies by several degrees and out-of-plane deformations reach 1 nm. The atomically thin single-crystal membranes offer ample scope for fundamental research and new technologies, whereas the observed corrugations in the third dimension may provide subtle reasons for the stability of two-dimensional crystals13,14,15.

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The structure of suspended graphene sheets

N G van Kampen 1981 Amsterdam: North-Holland xiv + 419 pp price Dfl 180 This is a book which, at a lower price, could be expected to become an essential part of the library of every physical scientist concerned with problems involving fluctuations and stochastic processes, as well as those who just enjoy a beautifully written book. It provides an extensive graduate-level introduction which is clear, cautious, interesting and readable.

https://iopscience.iop.org/article/10.1088/0031-9112/34/4/040/pdf

Stochastic Processes in Physics and Chemistry

Obtaining the exact multi-time correlations for one-dimensional growth models described by the Kardar-Parisi-Zhang (KPZ) universality class is presently an outstanding open problem. Here, we study the joint probability distribution function (JPDF) of the height of the KPZ equation with droplet initial conditions, at two different times $t_1<t_2$, in the limit where both times are large and their ratio $t_2/t_1$ is fixed. This maps to the JPDF of the free energies of two directed polymers with two different lengths and in the same random potential. Using the replica Bethe ansatz (RBA) method, we obtain the exact tail of the JPDF when one of its argument (the KPZ height at the earlier time $t_1$) is large and positive. Our formula interpolates between two limits where the JPDF decouples: (i) for $t_2/t_1 \to +\infty$ into a product of two GUE Tracy-Widom (TW) distributions, and (ii) for $t_2/t_1 \to 1^+$ into a product of a GUE-TW distribution and a Baik-Rains distribution (associated to stationary KPZ evolution). The lowest cumulants of the height at time $t_2$, conditioned on the one at time $t_1$, are expressed analytically as expansions around these limits, and computed numerically for arbitrary $t_2/t_1$. Moreover we compute the connected two-time correlation, conditioned to a large enough value at $t_1$, providing a quantitative prediction for the so-called persistence of correlations (or ergodicity breaking) in the time evolution from the droplet initial condition. Our RBA results are then compared with arguments based on Airy processes, with satisfactory agreement. These predictions are universal for all models in the KPZ class and should be testable in experiments and numerical simulations.

https://iopscience.iop.org/article/10.1088/1742-5468/aa6bce/pdf

Tail of the two-time height distribution for KPZ growth in one dimension

We show how our previous result based on the replica Bethe ansatz for the Kardar?Parisi?Zhang (KPZ) equation with the ?half-flat? initial condition leads to the Airy2 to Airy1 (i.e.?GUE (Gaussian unitary ensemble) to GOE (Gaussian orthogonal ensemble)) universal crossover one-point height distribution in the limit of large time. It involves a ?decoupling assumption? in that limit, validated by the result. Equivalently, we obtain the distribution of the free energy of a long directed polymer (DP) in a random potential with one fixed endpoint and the other one on a half-line. We generalize to a DP when each endpoint is free on its own half-line. This yields, in the large time limit, a conjecture for the distribution of the maximum of the transition process Airy2?1 (minus a half-parabola) on a half-line.

Crossover from droplet to flat initial conditions in the KPZ equation from the replica Bethe ansatz

We consider an active run-and-tumble particle (RTP) in d dimensions, starting from the origin and evolving over a time interval [0,t]. We examine three different models for the dynamics of the RTP: the standard RTP model with instantaneous tumblings, a variant with instantaneous runs and a general model in which both the tumblings and the runs are noninstantaneous. For each of these models, we use the Sparre Andersen theorem for discrete-time random walks to compute exactly the probability that the x component does not change sign up to time t, showing that it does not depend on d. As a consequence of this result, we compute exactly other x-component properties, namely, the distribution of the time of the maximum and the record statistics, showing that they are universal, i.e., they do not depend on d. Moreover, we show that these universal results hold also if the speed v of the particle after each tumbling is random, drawn from a generic probability distribution. Our findings are confirmed by numerical simulations. Some of these results have been announced in a recent Letter [Phys. Rev. Lett. 124, 090603 (2020)10.1103/PhysRevLett.124.090603].

Universal properties of a run-and-tumble particle in arbitrary dimension.

We consider a model of Dirac fermions coupled to flexural phonons to describe a graphene sheet fluctuating in dimension $2+d$. We derive the self-consistent screening equations for the quantum problem, exact in the limit of large $d$. We first treat the membrane alone, and work out the quantum to classical and harmonic to anharmonic crossovers. For the coupled electron-membrane problem, we calculate the dressed two-particle propagators of the elastic and electron interactions and find that it exhibits a collective mode which becomes unstable at some wave vector ${q}_{\mathrm{c}}$ for large enough coupling $g$. The saddle-point analysis, exact at large $d$, indicates that this instability corresponds to spontaneous and simultaneous appearance of Gaussian curvature and electron puddles. The relevance to ripples in graphene is discussed.

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Collective excitations in a large-d model for graphene

Analyse des relations de recursion du groupe de renormalisation obtenues par Chen et Lubensky pour le point multicritique associe aux fluctuations critiques simultanees dans l'ordre ferromagnetique et de verre de spin. Mise en evidence de certaines propriees universelles du point multicritique

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Pierre Le Doussal

Papers

Tail of the two-time height distribution for KPZ growth in one dimension

Crossover from droplet to flat initial conditions in the KPZ equation from the replica Bethe ansatz

Universal properties of a run-and-tumble particle in arbitrary dimension.

Collective excitations in a large-d model for graphene

ε expansion for the Nishimori multicritical point of spin glasses