This article reviews the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations. The Dirac electrons can be controlled by application of external electric and magnetic fields, or by altering sample geometry and/or topology. The Dirac electrons behave in unusual ways in tunneling, confinement, and the integer quantum Hall effect. The electronic properties of graphene stacks are discussed and vary with stacking order and number of layers. Edge (surface) states in graphene depend on the edge termination (zigzag or armchair) and affect the physical properties of nanoribbons. Different types of disorder modify the Dirac equation leading to unusual spectroscopic and transport properties. The effects of electron-electron and electron-phonon interactions in single layer and multilayer graphene are also presented.

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The electronic properties of graphene

Deposits of clastic carbonate-dominated (calciclastic) sedimentary slope systems in the rock record have been identified mostly as linearly-consistent carbonate apron deposits, even though most ancient clastic carbonate slope deposits fit the submarine fan systems better. Calciclastic submarine fans are consequently rarely described and are poorly understood. Subsequently, very little is known especially in mud-dominated calciclastic submarine fan systems. Presented in this study are a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) that reveals a >250 m thick calciturbidite complex deposited in a calciclastic submarine fan setting. Seven facies are recognised from core and thin section characterisation and are grouped into three carbonate turbidite sequences. They include: 1) Calciturbidites, comprising mostly of highto low-density, wavy-laminated bioclast-rich facies; 2) low-density densite mudstones which are characterised by planar laminated and unlaminated muddominated facies; and 3) Calcidebrites which are muddy or hyper-concentrated debrisflow deposits occurring as poorly-sorted, chaotic, mud-supported floatstones. These

Phd by thesis

It is possible to say that zeolites are the most widely used catalysts in industry They are crystalline microporous materials which have become extremely successful as catalysts for oil refining, petrochemistry, and organic synthesis in the production of fine and speciality chemicals, particularly when dealing with molecules having kinetic diameters below 10 A The reason for their success in catalysis is related to the following specific features of these materials:1 (1) They have very high surface area and adsorption capacity (2) The adsorption properties of the zeolites can be controlled, and they can be varied from hydrophobic to hydrophilic type materials (3) Active sites, such as acid sites for instance, can be generated in the framework and their strength and concentration can be tailored for a particular application (4) The sizes of their channels and cavities are in the range typical for many molecules of interest (5-12 A), and the strong electric fields2 existing in those micropores together with an electronic confinement of the guest molecules3 are responsible for a preactivation of the reactants (5) Their intricate channel structure allows the zeolites to present different types of shape selectivity, ie, product, reactant, and transition state, which can be used to direct a given catalytic reaction toward the desired product avoiding undesired side reactions (6) All of these properties of zeolites, which are of paramount importance in catalysis and make them attractive choices for the types of processes listed above, are ultimately dependent on the thermal and hydrothermal stability of these materials In the case of zeolites, they can be activated to produce very stable materials not just resistant to heat and steam but also to chemical attacks Avelino Corma Canos was born in Moncofar, Spain, in 1951 He studied chemistry at the Universidad de Valencia (1967−1973) and received his PhD at the Universidad Complutense de Madrid in 1976 He became director of the Instituto de Tecnologia Quimica (UPV-CSIC) at the Universidad Politecnica de Valencia in 1990 His current research field is zeolites as catalysts, covering aspects of synthesis, characterization and reactivity in acid−base and redox catalysis A Corma has written about 250 articles on these subjects in international journals, three books, and a number of reviews and book chapters He is a member of the Editorial Board of Zeolites, Catalysis Review Science and Engineering, Catalysis Letters, Applied Catalysis, Journal of Molecular Catalysis, Research Trends, CaTTech, and Journal of the Chemical Society, Chemical Communications A Corma is coauthor of 20 patents, five of them being for commercial applications He has been awarded with the Dupont Award on new materials (1995), and the Spanish National Award “Leonardo Torres Quevedo” on Technology Research (1996) 2373 Chem Rev 1997, 97, 2373−2419

From Microporous to Mesoporous Molecular-Sieve Materials and Their Use in Catalysis

Graphene — a recently isolated one-atom-thick layered form of graphite — is a hot topic in the materials science and condensed matter physics communities, where it is proving to be a popular model system for investigation. An experiment involving individual graphene sheets suspended over a microscale scaffold has allowed structure determination using transmission electron microscopy and diffraction, perhaps paving the way towards an answer to the question of why graphene can exist at all. The 'two-dimensional' sheets, it seems, are not flat, but wavy. The undulations are less pronounced in a two-layer system, and disappear in multilayer samples. Learning more about this 'waviness' may reveal what makes these extremely thin carbon membranes so stable. Investigations of individual graphene sheets freely suspended on a microfabricated scaffold in vacuum or in air reveal that the membranes are not perfectly flat, but exhibit an intrinsic waviness, such that the surface normal varies by several degrees, and out-of-plane deformations reach 1 nm. The recent discovery of graphene has sparked much interest, thus far focused on the peculiar electronic structure of this material, in which charge carriers mimic massless relativistic particles1,2,3. However, the physical structure of graphene—a single layer of carbon atoms densely packed in a honeycomb crystal lattice—is also puzzling. On the one hand, graphene appears to be a strictly two-dimensional material, exhibiting such a high crystal quality that electrons can travel submicrometre distances without scattering. On the other hand, perfect two-dimensional crystals cannot exist in the free state, according to both theory and experiment4,5,6,7,8,9. This incompatibility can be avoided by arguing that all the graphene structures studied so far were an integral part of larger three-dimensional structures, either supported by a bulk substrate or embedded in a three-dimensional matrix1,2,3,9,10,11,12. Here we report on individual graphene sheets freely suspended on a microfabricated scaffold in vacuum or air. These membranes are only one atom thick, yet they still display long-range crystalline order. However, our studies by transmission electron microscopy also reveal that these suspended graphene sheets are not perfectly flat: they exhibit intrinsic microscopic roughening such that the surface normal varies by several degrees and out-of-plane deformations reach 1 nm. The atomically thin single-crystal membranes offer ample scope for fundamental research and new technologies, whereas the observed corrugations in the third dimension may provide subtle reasons for the stability of two-dimensional crystals13,14,15.

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The structure of suspended graphene sheets

N G van Kampen 1981 Amsterdam: North-Holland xiv + 419 pp price Dfl 180 This is a book which, at a lower price, could be expected to become an essential part of the library of every physical scientist concerned with problems involving fluctuations and stochastic processes, as well as those who just enjoy a beautifully written book. It provides an extensive graduate-level introduction which is clear, cautious, interesting and readable.

https://iopscience.iop.org/article/10.1088/0031-9112/34/4/040/pdf

Stochastic Processes in Physics and Chemistry

We unveil a remarkable connection between the sine-Gordon quantum field theory and the Kardar-Parisi-Zhang (KPZ) growth equation. We find that the non-relativistic limit of the two-point correlation function of the sine-Gordon theory is related to the generating function of the height distribution of the KPZ field with droplet initial conditions, i.e. the directed polymer free energy with two endpoints fixed. As shown recently, the latter can be expressed as a Fredholm determinant which in the large-time separation limit converges to the GUE Tracy-Widom cumulative distribution. Possible applications and extensions are discussed.

https://iopscience.iop.org/article/10.1209/0295-5075/107/10011/pdf

From the sine-Gordon field theory to the Kardar-Parisi-Zhang growth equation

We examine here various aspects of the statics and dynamics of disordered elastic systems such as manifolds and periodic systems. Although these objects look very similar and indeed share some underlying physics, periodic systems constitute a class of their own with markedly different properties. We focus on such systems, review the methods allowing to treat them, emphasize the shift of viewpoint compared to the physics of manifolds and discuss their physics in detail. As for the statics, periodicity helps the system to retain a quasi-translational order and to be stable with respect to the proliferation of free topological defects such as dislocations. A disordered periodic system thus leads to a glass phase with Bragg peaks: the Bragg glass. On the other hand, for driven lattices, transverse periodicity allows the system to retain its glassy nature, leading to a moving glass phase. The existence of these two phases has important theoretical and experimental consequences, in particular for vortex physics in superconductors, the physical system which is mainly focused here.

Statics and Dynamics of Disordered Elastic Systems

We compute the Functional Renormalization Group (FRG) disorder-correlator function R(v) for d-dimensional elastic manifolds pinned by a random potential in the limit of infinite embedding space dimension N. It measures the equilibrium response of the manifold in a quadratic potential well as the center of the well is varied from 0 to v. We find two distinct scaling regimes: (i) a “single shock” regime, v 2 ∼ L −d where L d is the system volume and (ii) a “thermodynamic” regime, v 2 ∼ N. In regime (i) all the equivalent replica symmetry breaking (RSB) saddle points within the Gaussian variational approximation contribute, while in regime (ii) the effect of RSB enters only through a single anomaly. When the RSB is continuous (e.g., for short-range disorder, in dimension 2 ≤ d ≤ 4), we prove that regime (ii) yields the large-N FRG function obtained previously. In that case, the disorder correlator exhibits a cusp in both regimes, though with different amplitudes and of different physical origin. When the RSB solution is 1-step and non-marginal (e.g., d < 2 for SR disorder), the correlator R(v) in regime (ii) is considerably reduced, and exhibits no cusp. Solutions of the FRG flow corresponding to non-equilibrium states are discussed as well. In all cases the regime (i) exhibits a cusp non-analyticity at T = 0, whose form and thermal rounding at finite T is obtained exactly and interpreted in terms of shocks. The results are compared with previous work, and consequences for manifolds at finite N, as well as extensions to spin glasses and related models are discussed. PACS numbers:

/pdf/cusps-and-shocks-in-the-renormalized-potential-of-glassy-282cq6v6i1.pdf

Cusps and shocks in the renormalized potential of glassy random manifolds: How Functional Renormalization Group and Replica Symmetry Breaking fit together

We study the 2D vortex-free XY model in a random field, a model for randomly pinned flux lines in a plane. We construct controlled RG recursion relations which allow for replica symmetry breaking (RSB). The fixed point previously found by Cardy and Ostlund in the glass phase $T<T_c$ is {\it unstable} to RSB. The susceptibility $\chi$ associated to infinitesimal RSB perturbation in the high-temperature phase is found to diverge as $\chi \propto (T-T_c)^{-\gamma}$ when $T \rightarrow T_c^{+}$. This provides analytical evidence that RSB occurs in finite dimensional models. The physical consequences for the glass phase are discussed.

Pierre Le Doussal

Papers

From the sine-Gordon field theory to the Kardar-Parisi-Zhang growth equation

Statics and Dynamics of Disordered Elastic Systems

Cusps and shocks in the renormalized potential of glassy random manifolds: How Functional Renormalization Group and Replica Symmetry Breaking fit together

Statics and Dynamics of Disordered Elastic Systems

Replica Symmetry Breaking Instability in the 2D XY Model in a Random Field.