This article reviews the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations. The Dirac electrons can be controlled by application of external electric and magnetic fields, or by altering sample geometry and/or topology. The Dirac electrons behave in unusual ways in tunneling, confinement, and the integer quantum Hall effect. The electronic properties of graphene stacks are discussed and vary with stacking order and number of layers. Edge (surface) states in graphene depend on the edge termination (zigzag or armchair) and affect the physical properties of nanoribbons. Different types of disorder modify the Dirac equation leading to unusual spectroscopic and transport properties. The effects of electron-electron and electron-phonon interactions in single layer and multilayer graphene are also presented.

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The electronic properties of graphene

Deposits of clastic carbonate-dominated (calciclastic) sedimentary slope systems in the rock record have been identified mostly as linearly-consistent carbonate apron deposits, even though most ancient clastic carbonate slope deposits fit the submarine fan systems better. Calciclastic submarine fans are consequently rarely described and are poorly understood. Subsequently, very little is known especially in mud-dominated calciclastic submarine fan systems. Presented in this study are a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) that reveals a >250 m thick calciturbidite complex deposited in a calciclastic submarine fan setting. Seven facies are recognised from core and thin section characterisation and are grouped into three carbonate turbidite sequences. They include: 1) Calciturbidites, comprising mostly of highto low-density, wavy-laminated bioclast-rich facies; 2) low-density densite mudstones which are characterised by planar laminated and unlaminated muddominated facies; and 3) Calcidebrites which are muddy or hyper-concentrated debrisflow deposits occurring as poorly-sorted, chaotic, mud-supported floatstones. These

Phd by thesis

It is possible to say that zeolites are the most widely used catalysts in industry They are crystalline microporous materials which have become extremely successful as catalysts for oil refining, petrochemistry, and organic synthesis in the production of fine and speciality chemicals, particularly when dealing with molecules having kinetic diameters below 10 A The reason for their success in catalysis is related to the following specific features of these materials:1 (1) They have very high surface area and adsorption capacity (2) The adsorption properties of the zeolites can be controlled, and they can be varied from hydrophobic to hydrophilic type materials (3) Active sites, such as acid sites for instance, can be generated in the framework and their strength and concentration can be tailored for a particular application (4) The sizes of their channels and cavities are in the range typical for many molecules of interest (5-12 A), and the strong electric fields2 existing in those micropores together with an electronic confinement of the guest molecules3 are responsible for a preactivation of the reactants (5) Their intricate channel structure allows the zeolites to present different types of shape selectivity, ie, product, reactant, and transition state, which can be used to direct a given catalytic reaction toward the desired product avoiding undesired side reactions (6) All of these properties of zeolites, which are of paramount importance in catalysis and make them attractive choices for the types of processes listed above, are ultimately dependent on the thermal and hydrothermal stability of these materials In the case of zeolites, they can be activated to produce very stable materials not just resistant to heat and steam but also to chemical attacks Avelino Corma Canos was born in Moncofar, Spain, in 1951 He studied chemistry at the Universidad de Valencia (1967−1973) and received his PhD at the Universidad Complutense de Madrid in 1976 He became director of the Instituto de Tecnologia Quimica (UPV-CSIC) at the Universidad Politecnica de Valencia in 1990 His current research field is zeolites as catalysts, covering aspects of synthesis, characterization and reactivity in acid−base and redox catalysis A Corma has written about 250 articles on these subjects in international journals, three books, and a number of reviews and book chapters He is a member of the Editorial Board of Zeolites, Catalysis Review Science and Engineering, Catalysis Letters, Applied Catalysis, Journal of Molecular Catalysis, Research Trends, CaTTech, and Journal of the Chemical Society, Chemical Communications A Corma is coauthor of 20 patents, five of them being for commercial applications He has been awarded with the Dupont Award on new materials (1995), and the Spanish National Award “Leonardo Torres Quevedo” on Technology Research (1996) 2373 Chem Rev 1997, 97, 2373−2419

From Microporous to Mesoporous Molecular-Sieve Materials and Their Use in Catalysis

Graphene — a recently isolated one-atom-thick layered form of graphite — is a hot topic in the materials science and condensed matter physics communities, where it is proving to be a popular model system for investigation. An experiment involving individual graphene sheets suspended over a microscale scaffold has allowed structure determination using transmission electron microscopy and diffraction, perhaps paving the way towards an answer to the question of why graphene can exist at all. The 'two-dimensional' sheets, it seems, are not flat, but wavy. The undulations are less pronounced in a two-layer system, and disappear in multilayer samples. Learning more about this 'waviness' may reveal what makes these extremely thin carbon membranes so stable. Investigations of individual graphene sheets freely suspended on a microfabricated scaffold in vacuum or in air reveal that the membranes are not perfectly flat, but exhibit an intrinsic waviness, such that the surface normal varies by several degrees, and out-of-plane deformations reach 1 nm. The recent discovery of graphene has sparked much interest, thus far focused on the peculiar electronic structure of this material, in which charge carriers mimic massless relativistic particles1,2,3. However, the physical structure of graphene—a single layer of carbon atoms densely packed in a honeycomb crystal lattice—is also puzzling. On the one hand, graphene appears to be a strictly two-dimensional material, exhibiting such a high crystal quality that electrons can travel submicrometre distances without scattering. On the other hand, perfect two-dimensional crystals cannot exist in the free state, according to both theory and experiment4,5,6,7,8,9. This incompatibility can be avoided by arguing that all the graphene structures studied so far were an integral part of larger three-dimensional structures, either supported by a bulk substrate or embedded in a three-dimensional matrix1,2,3,9,10,11,12. Here we report on individual graphene sheets freely suspended on a microfabricated scaffold in vacuum or air. These membranes are only one atom thick, yet they still display long-range crystalline order. However, our studies by transmission electron microscopy also reveal that these suspended graphene sheets are not perfectly flat: they exhibit intrinsic microscopic roughening such that the surface normal varies by several degrees and out-of-plane deformations reach 1 nm. The atomically thin single-crystal membranes offer ample scope for fundamental research and new technologies, whereas the observed corrugations in the third dimension may provide subtle reasons for the stability of two-dimensional crystals13,14,15.

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The structure of suspended graphene sheets

N G van Kampen 1981 Amsterdam: North-Holland xiv + 419 pp price Dfl 180 This is a book which, at a lower price, could be expected to become an essential part of the library of every physical scientist concerned with problems involving fluctuations and stochastic processes, as well as those who just enjoy a beautifully written book. It provides an extensive graduate-level introduction which is clear, cautious, interesting and readable.

https://iopscience.iop.org/article/10.1088/0031-9112/34/4/040/pdf

Stochastic Processes in Physics and Chemistry

We study the dynamics of a polymer or a D-dimensional elastic manifold diffusing and convected in a non-potential static random flow (the ``randomly driven polymer model''). We find that short-range (SR) disorder is relevant for d 2 and the velocity versus applied force characteristics is sublinear, i.e. at small forces v(f) f^phi with phi > 1. It indicates that this new state is glassy, with dynamically generated barriers leading to trapping, even by a divergenceless (transversal) flow. For random flows with long-range (LR) correlations, we find continuously varying exponents with the ratio gL/gT of potential to transversal disorder, and interesting crossover phenomena between LR and SR behavior. For isotropic polymers new effects (e.g. a sign change of zeta - zeta_0) result from the competition between localization and stretching by the flow. In contrast to purely potential disorder, where the dynamics gets frozen, here the dynamical exponent z is not much larger than 2, making it easily accessible by simulations. The phenomenon of pinning by transversal disorder is further demonstrated using a two monomer ``dumbbell'' toy model.

Polymers and manifolds in static random flows: a renormalization group study

We conjecture the universal probability distribution at large time for the one-point height in the 1D Kardar-Parisi-Zhang (KPZ) stochastic growth universality class, with initial conditions interpolating from any one of the three main classes (droplet, flat, stationary) on the left, to another on the right, allowing for drifts and also for a step near the origin. The result is obtained from a replica Bethe ansatz calculation starting from the KPZ continuum equation, together with a "decoupling assumption" in the large time limit. Some cases are checked to be equivalent to previously known results from other models in the same class, which provides a test of the method, others appear to be new. In particular we obtain the crossover distribution between flat and stationary initial conditions (crossover from Airy$_1$ to Airy$_{{\rm stat}}$) in a simple compact form.

Crossover between various initial conditions in KPZ growth: flat to stationary

Brownian particles that are replicated and annihilated at equal rate have strongly correlated positions, forming a few compact clusters separated by large gaps. We characterize the distribution of the particles at a given time, using a definition of clusters in terms of a coarse-graining length recently introduced by some of us. We show that, in a non-extinct realization, the average number of clusters grows as ∼tDf/2 where Df≈0.22 is the Hausdorff dimension of the boundary of the super-Brownian motion (SBM), found by Mueller, Mytnik, and Perkins. We also compute the distribution of gaps between consecutive particles. We find two regimes separated by the characteristic length scale ℓ=D/β where D is the diffusion constant and β the branching rate. The average number of gaps greater than g decays as ∼gDf−2 for g≪ℓ and ∼g−Df for g≫ℓ . Finally, conditioned on the number of particles n, the above distributions are valid for g≪n ; the average number of gaps greater than g≫n is much less than one, and decays as ≃4(g/n)−2 , in agreement with the universal gap distribution predicted by Ramola, Majumdar, and Schehr. Our results interpolate between a dense SBM regime and a large-gap regime, unifying two previously independent approaches.

Clusters in the critical branching Brownian motion

We study the average density of $N$ spinless noninteracting fermions in a $2d$ harmonic trap rotating with a constant frequency $\Omega$ and in the presence of an additional repulsive central potential $\gamma/r^2$. The average density at zero temperature was recently studied in Phys. Rev. A $\textbf{103}$, 033321 (2021) and an interesting multi-layered"wedding cake"structure with a"hole"at the center was found for the density in the large $N$ limit. In this paper, we study the average density at finite temperature. We demonstrate how this"wedding-cake"structure is modified at finite temperature. These large $N$ results warrant going much beyond the standard Local Density Approximation. We also generalize our results to a wide variety of trapping potentials and demonstrate the universality of the associated scaling functions both in the bulk and at the edges of the"wedding-cake".

Density profile of noninteracting fermions in a rotating two-dimensional trap at finite temperature

We study the statics and dynamics of an elastic manifold in a disordered medium with quenched defects correlated as approximately r{-a} for large separation r. We derive the functional renormalization-group equations to one-loop order, which allow us to describe the universal properties of the system in equilibrium and at the depinning transition. Using a double epsilon=4-d and delta=4-a expansion we compute the fixed points characterizing different universality classes and analyze their regions of stability. The long-range disorder-correlator remains analytic but generates short-range disorder whose correlator exhibits the usual cusp. The critical exponents and universal amplitudes are computed to first order in epsilon and delta at the fixed points. At depinning, a velocity-versus-force exponent beta larger than unity can occur. We discuss possible realizations using extended defects.

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Pierre Le Doussal

Papers

Polymers and manifolds in static random flows: a renormalization group study

Crossover between various initial conditions in KPZ growth: flat to stationary

Clusters in the critical branching Brownian motion

Density profile of noninteracting fermions in a rotating two-dimensional trap at finite temperature

Statics and dynamics of elastic manifolds in media with long-range correlated disorder