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Pin-Wen Huang

Researcher at Zhejiang University

Publications -  10
Citations -  117

Pin-Wen Huang is an academic researcher from Zhejiang University. The author has contributed to research in topics: Density functional theory & Chemistry. The author has an hindex of 4, co-authored 7 publications receiving 70 citations. Previous affiliations of Pin-Wen Huang include Chinese Academy of Sciences.

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Journal ArticleDOI

Uncovering the impact of ‘capsule’ shaped amine-type ligands on Am(III)/Eu(III) separation

TL;DR: This study might provide new insights into understanding the selectivity of the amine-type ligands toward minor actinides, and pave the way for designing new TPEN derivatives for extraction and separation of An(iii)/Ln(iii).
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Understanding Am3+/Cm3+ separation with H4TPAEN and its hydrophilic derivatives: a quantum chemical study

TL;DR: The Am3+/Cm3+ selectivity of H4TPAEN and its two hydrophilic derivatives may be ascribed to the competition between the An-N and An-O interactions and the few dissimilarities in their geometrical structures.
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Theoretical studies on the synergistic extraction of Am3+ and Eu3+ with CMPO-HDEHP and CMPO-HEH[EHP] systems.

TL;DR: It is found that hydrogen bonds between neutral and acid ligands may greatly influence the Eu3+/Am3+ extraction and separation performance of the two synergistic systems.
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Hydrophilic Sulfonated 2,9-Diamide-1,10-phenanthroline Endowed with a Highly Effective Ligand for Separation of Americium(III) from Europium(III): Extraction, Spectroscopy, and Density Functional Theory Calculations

TL;DR: A novel hydrophilic multidentate ligand is designed and synthesized: disulfonated N,N'-diphenyl-2,9-diamide-1,10-phenanthroline (DS-Ph-DAPhen) with soft and hard donor atoms, as a masking agent in aqueous solutions for Am(III) separation.
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Enhancing the Am3+/Cm3+ separation ability by weakening the binding affinity of N donor atoms: a comparative theoretical study of N, O combined extractants.

TL;DR: In this paper, three N, O combined extractants 2,6-pyridinedicarboxylic acid di(N-ethyl-4-fluoroanilide) (Et(pFPh)DPA), diphenyl(2 pyridyl)phosphine oxide (Ph2PyPO), and alkyldiamide amine with 2-ethylhexylalkyl chains (ADAAM(EH)) have been identified to exhibit selectivity for Am3+ over Cm3+.