Q
Qian Wang
Researcher at École Polytechnique Fédérale de Lausanne
Publications - 184
Citations - 5564
Qian Wang is an academic researcher from École Polytechnique Fédérale de Lausanne. The author has contributed to research in topics: Catalysis & Enantioselective synthesis. The author has an hindex of 39, co-authored 173 publications receiving 4204 citations. Previous affiliations of Qian Wang include Peking University & Beijing University of Technology.
Papers
More filters
Journal ArticleDOI
Copper‐Catalyzed Cyanomethylation of Allylic Alcohols with Concomitant 1,2‐Aryl Migration: Efficient Synthesis of Functionalized Ketones Containing an α‐Quaternary Center
TL;DR: The protocol provided an efficient route to functionalized ketones containing an α-quaternary center and suggested that 1,2-aryl migration proceeded through a radical pathway (neophyl rearrangement).
Journal ArticleDOI
Still Unconquered: Enantioselective Passerini and Ugi Multicomponent Reactions
TL;DR: A chiral phosphoric acid (CPA)-catalyzed enantioselective three-component synthesis of 2-(1-aminoalkyl)-5-AMinooxazoles, a four- component synthesis of epoxy-tetrahydropyrrolo and the progress recorded in this field over the past 15 years is summarized.
Journal ArticleDOI
Palladium-Catalyzed Through-Space C(sp3)H and C(sp2)H Bond Activation by 1,4-Palladium Migration: Efficient Synthesis of [3,4]-Fused Oxindoles†
TL;DR: Palladium two step: Linear anilides were converted into the title compounds in good to excellent yields through a palladium-catalyzed domino carbopalladation/1,4-palladium shift sequence.
Journal ArticleDOI
Copper-Catalyzed Arylation of Remote C(sp3 )-H Bonds in Carboxamides and Sulfonamides.
TL;DR: Mechanistic studies indicate that the reaction might proceed through an amidyl radical generation, 1,5-hydrogen atom transfer (HAT), and copper-catalyzed cross-coupling of the resulting carbon radical with arylboronic acids.
Journal ArticleDOI
Palladium-Catalyzed Enantioselective Domino Heck/Intermolecular C–H Bond Functionalization: Development and Application to the Synthesis of (+)-Esermethole
TL;DR: Intramolecular asymmetric carbopalladation of N-aryl acrylamides followed by intermolecular trapping of the resulting σ-C(sp(3))-Pd complex by azoles afforded 3,3-disubstituted oxindoles in good yields with excellent enantioselectivities.