Ratna Chauhan

TL;DR: Nine new transition-metal dithiocarbamates involving ferrocene (Fc), namely, [M(FcCH(2)Bzdtc)(2)] (M=Ni(II) (1) and UO (2) (VI) (9), have been synthesised and characterised by micro analyses, IR spectroscopy, (13)C NMR spectroscopic, and in three cases by single-crystal X-ray analysis

TL;DR: The X-ray structural analyses reveal the existence of rare M···H-C intermolecular anagostic interactions involving the metal atom in chain motifs in 1 and 4, which are retained in solution as evidenced by (1)H NMR spectroscopy.

TL;DR: Two new heterobimetallic phenylmercury(ii) dithiocarbamate complexes incorporating the ferrocenyl moiety, prepared and characterized by elemental analysis, UV-Vis, IR, (1)H and (13)C NMR spectroscopies, suggest that the delocalization of electron spin population can affect the magnitude of ΔE(p.

TL;DR: Two new compounds, FcCH=NC(6)H(4)COOH (1) and Fc CH=NCH( 2)CH(2)OH (2) (Fc=C(5)H (4)FeC (5) H(5)), have been synthesized and characterized by elemental analyses, IR and (1]H NMR spectroscopy, and ESI-MS.

TL;DR: One heteroleptic Ni(II)dppe dithiocarbamate complex cation [Ni{S2CN(CH2)4CHOH)}(dppe)]+ with three different counter anions viz PF6−(1), BPh4− (2) and BF4−(3) have been synthesized and characterized by microanalysis, IR, UV-Vis, 1H, 13C and 31P NMR spectroscopy and X-ray crystallography as mentioned in this paper.