Showing papers in "Inorganica Chimica Acta in 2014"

TL;DR: Most of the organotin(IV) carboxylates discussed in this review have greater anticancer activity against different cell lines than do the standard drugs.

TL;DR: The progress made in the past decade by organotin compounds as antitumor chemotherapeutic agents is reflected and the landmarks for their future projections in drug industry are explored.

TL;DR: In this paper, a substituted dithiocarbazate moiety has been prepared using 4-picolylchloride hydrochloride to obtain S-4picolyldithionic carbazate (S4PDTC) and its by-product S4diPDTC.

TL;DR: In this paper, the Co(II) complex, trans-[Co(Pir)2(DMF)2], where Pir is piroxicam, has been prepared in two different ionic liquids and fully characterized.

TL;DR: In this paper, size-controlled crystalline basic nanoporous coordination polymers of IRMOF-3 (Zn4O(H2N-TA)3) and its catalytically study for synthesis of tetrahydro-chromenes was investigated.

TL;DR: In this article, 16 new energetic ionic ferrocene compounds, [FcCH2N(CH3)2(CnH2n+1]-X− (Fc−= ferrocenyl; X−−=nitrate or picrate anion; n−= 3−10), were synthesized in high yields and characterized by 1H NMR, 13C NMR and UV-Vis, elementary analysis, TG and DSC methods.

TL;DR: Wang et al. as mentioned in this paper reviewed and analyzed 829 cases of organotin(IV) poisoned patients in China, and found that organotins are the obvious risky factors of environmental contamination.

TL;DR: In this paper, a series of salen type Schiff base ligands and their mononuclear (CuLn, n −1−4) or dinuclear Cu(II) complexes were synthesized and characterized by 1H NMR, IR and UV-Vis spectroscopy as well as elemental analyses.

TL;DR: In this article, a pincer-type ligand featuring two ionizable pyrazole NH groups, 2,6-bis(5- tert -butyl-1 H -pyrazol-3-yl)pyridine (LH 2 ) and derivatization of these complexes were described.

TL;DR: In this article, the synthesis, characterization, catechol oxidase activity, electrochemistry and electrospray ionization mass spectroscopy (ESI-MS positive) of five mononuclear manganese(III) compounds [MnIIIL(OAc)(H2O)]·DMF (1), [mnIIil(Cl)(H 2O), 2H 2 O ), [mnc2O(2H 2 )·2O (2), [Mnc3O(N3), H2O), [

TL;DR: A perfectly linear trinuclear zinc(II) complex [Zn3L2(μ-O2CCH3)2] (1) containing a (N,O)-donor Schiff base ligand, (H2L = N,N′-bis(salicyaldehydene)-1,3-diaminopropan-2-ol) has been synthesized and characterized by single crystal X-ray diffraction study.

TL;DR: In this article, the synthesis, characterization and antifungal activity of the complexes were described, and the results were compared with those of nystatin and miconazole nitrate, used as control drugs.

TL;DR: In this paper, the binding of vanadium to hTF in the oxidation states +5 and +3 was investigated and the possibility of up-take of vanadate by cells through (Fe III ) 2 hTF endocytosis was suggested.

TL;DR: In this paper, seven new coordination polymers, namely, Ni(L)1.5(2-CMSN)(H2O), Co2(L), 2(2CMSN)2(H 2O), H2O 2, [Cd(L)(2-cMSN)3 [Zn(L, 2-CMSN]), H2ADTZ], H2N, H2ODTZ, [H2N], [HN] 3, HN 4], HN 5, HNO 6, H

TL;DR: In this article, the magnetic Fe3O4 nanoparticles were prepared by co-precipitation method and coated with oleic acid and used for the immobilization of palladium particles to produce Fe@OA-Pd.

TL;DR: In this paper, a series of nitrile-functionalized N-heterocyclic carbene (NHC) proligands based on N-methyl-N′-benzonitrile and N,N´-dibenzonitrile imidazolium salts, 1-4, has been developed and investigated.

TL;DR: In this article, three ternary lanthanide complexes with o-bromobenzoic (o-BrBA), o-chlorobenzzoic acid (O-ClBA), and 2,4,6-tri(2-pyridyl)-s-triazine (TPTZ) have been synthesized.

TL;DR: One heteroleptic Ni(II)dppe dithiocarbamate complex cation [Ni{S2CN(CH2)4CHOH)}(dppe)]+ with three different counter anions viz PF6−(1), BPh4− (2) and BF4−(3) have been synthesized and characterized by microanalysis, IR, UV-Vis, 1H, 13C and 31P NMR spectroscopy and X-ray crystallography as mentioned in this paper.

TL;DR: In this article, two new corrole derivatives 2 and 3 were successfully synthetized and characterized by elemental analysis, 1 H-NMR, MALDI-TOF-MS, UV-Vis absorption and emission spectra.

TL;DR: In this paper, the synthesis and characterization of new complexes of 2-aminobenzothiazole (Habt) and ClO4 were reported, which are more cytotoxic than is cisplatin to human breast cancer (MDA-MB231) and human ovarian cancer (OVCAR-8) cell lines.

TL;DR: In this paper, the interaction of three potential anti-diabetic V IV O compounds formed by picolinate (pic), 3-methylpicolinate(3-mepic) and 6-methylic acid (6-mepsic) with hemoglobin (Hb) and red blood cells was studied with the combined application of spectroscopic (EPR), spectrophotometric (UV-Vis) and computational (DFT methods) techniques.

TL;DR: In this paper, the reaction of cobalt(II) perchlorate hexahydrate with a potentially tetradentate Schiff base ligand, HL (2-methoxy-6-(2-diethylaminoethylimino)methyl]phenol) in presence of sodium azide and sodium thiocyanate yields two complexes Co(L)( HL)(N-3)]center dot ClO4 ( 1) and Co( L)( HL) center dot Cl O4 ( 2); both being characterized by different physicochemical methods.

TL;DR: In this article, a review of achievements in the design, synthesis, characterization, and application of multinuclear coordination complexes in the years 2011-2013 is presented. And examples of their structural interconversion within dynamic combinatorial libraries are also presented.

TL;DR: The state of the art of liquid-crystalline metallodendrimers, i.e. metal-containing dendritic molecules displaying mesomorphic properties, is reviewed in this article.

TL;DR: The organotin(IV) compounds Me2SnCl2(dbtp) as mentioned in this paper, Me2snCl2dbtp)(1), Me2SNCl2dpttp)2 (2), Et2Ncl2dtp(3), EtNCl2Dpttp(4), NNCl 2dptp(5), nBuCl2nCl2btp(6), nNClCl2p(7), NCl2c2c(8), Ph2NCl(EtOH)2c), Ph

TL;DR: In this article, the synthesis and catalytic activity of nickel metallodendrimers (C1−C6) were reported, which were synthesized by the coordination of the metal precursors, Ni(OAc)2 and Ni(DME)Br2, to the periphery of salicylaldimine and iminopyridyl modified dendritic ligands.

TL;DR: In this paper, the authors focus on the host-guest chemistry of metallacyclic Pd II /Pt II -receptors and show how effective complexation of aromatic substrates, including some of environmental significance, can be achieved by a careful selection of the ligands and metal centers involved in the self-assembly processes.

TL;DR: In this article, a mouse model with vanadium pentoxide (V 2 O 5 ) inhalation was used to investigate the effect of V 2 O5 on the alveoli, pulmonary capillaries, and systemic circulation.

TL;DR: In this article, the authors reported the preparation and characterization of four novel gold(I) complexes containing tertiary phosphine and 3-benzyl-1,3-thiazolidine-2-thione.

TL;DR: In this article, three neat complexes (VVO2(acpy-bhz), VVO2 (acpy)-inh), and VVO 2(ACpy-nah) are isolated through covalent bonding of imidazolomethylpolystyrene, obtained by reacting chloromethymened polystyrene cross-linked with 5% divinylbenzene with imidazeole, with the corresponding neat complexes 1-3.