Rebecca L. Siegelman

TL;DR: A family of robust tetraamine-functionalized frameworks that retain cooperativity are reported, leading to the potential for exceptional efficiency in capturing CO2 under the extreme conditions relevant to natural gas flue emissions.

TL;DR: A detailed investigation of nine diamine-appended variants of the metal-organic framework Mg2(dobpdc4- = 4,4'-dioxidobiphenyl-3,3'-dicarboxylate) that feature step-shaped CO2 adsorption isotherms resulting from cooperative and reversible insertion of CO2 into metal-amine bonds to form ammonium carbamate chains highlights their potential as next-generation adsorbents for a wide array of

TL;DR: In this article, the development of porous materials as next-generation sorbents for CO2 capture applications is reviewed, focusing on stream-and sector-specific challenges while highlighting case studies within the context of rapidly shifting energy landscape.

TL;DR: Solid-state 13C NMR spectra and single-crystal X-ray diffraction structures of the Zn analogue reveal that this material adsorbs CO2 via formation of both ammonium carbamates and carbamic acid pairs, the latter of which are crystallographically verified for the first time in a porous material.

TL;DR: In this article, the hydrogen storage properties of a new family of isostructural metal-organic frameworks are reported, which are analogous to the widely studied M2(dobdc) analogues, featuring the same weak-field oxo-based ligand environment for the M2+ metal centers.