S
Sébastien Blanchard
Researcher at Centre national de la recherche scientifique
Publications - 17
Citations - 376
Sébastien Blanchard is an academic researcher from Centre national de la recherche scientifique. The author has contributed to research in topics: Chemistry & Catalysis. The author has an hindex of 7, co-authored 10 publications receiving 323 citations. Previous affiliations of Sébastien Blanchard include University of Paris & Pierre-and-Marie-Curie University.
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Journal ArticleDOI
Non‐Innocent Ligands: New Opportunities in Iron Catalysis
Sébastien Blanchard,Etienne Derat,Marine Desage-El Murr,Louis Fensterbank,Max Malacria,Virginie Mouriès-Mansuy +5 more
TL;DR: In this paper, the chemistry and applications of low-valent iron complexes bearing potentially non-innocent ligands are discussed. But the focus of this review is not on the catalytic properties of these complexes.
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Synthesis and characterization of the Keggin-type ruthenium-nitrido derivative [PW11O39{RuN}]4- and evidence of its electrophilic reactivity.
Vanina Lahootun,Claire Besson,Richard Villanneau,F. Villain,Lise-Marie Chamoreau,Kamal Boubekeur,Sébastien Blanchard,René Thouvenot,Anna Proust +8 more
TL;DR: The phosphoraniminato derivative [PW11O39{RuVNPh3}]3- has been structurally characterized and its unusual oxidation state is in accordance with its EPR spectrum.
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Iminosemiquinone radical ligands enable access to a well-defined redox-active Cu(II)-CF₃ complex.
Jérémy Jacquet,Elise Salanouve,Maylis Orio,Hervé Vezin,Sébastien Blanchard,Etienne Derat,Marine Desage-El Murr,Louis Fensterbank +7 more
TL;DR: Reactivity of this complex leads to nucleophilic trifluoromethylation of the ligand, suggesting an electronic interplay that results in a formal umpolung of the initial CF3(+) source.
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Electro-Assisted Reduction of CO2 to CO and Formaldehyde by (TOA)6[α-SiW11O39Co(_)] Polyoxometalate
Marcelo Girardi,Sébastien Blanchard,Sophie Griveau,Philippe Simon,Marc Fontecave,Fethi Bedioui,Anna Proust +6 more
TL;DR: In this paper, the multiproton-multielectron electrochemical reduction of CO2 in homogeneous solution by using (TOA)6[α-SiW11O39Co) polyoxometalate as an electrocatalyst was reported.
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Addition of N-heterocyclic carbenes to a ruthenium(VI) nitrido polyoxometalate: a new route to cyclic guanidines.
Claire Besson,Jean-Hugues Mirebeau,Jean-Hugues Mirebeau,Séverine Renaudineau,Sylvain Roland,Sébastien Blanchard,Hervé Vezin,Christine Courillon,Anna Proust,Anna Proust +9 more
TL;DR: The scope of N-atom transfer from the electrophilic ruthenium(VI) nitrido containing polyoxometalate has been extended to the N-heterocyclic carbene and the coupling product {CH(2)(Mes)N}(2)CNH(2%) characterized by (1)H NMR and high-resolution mass spectrometry.