S
Shiro Hikichi
Researcher at Kanagawa University
Publications - 113
Citations - 3803
Shiro Hikichi is an academic researcher from Kanagawa University. The author has contributed to research in topics: Ligand & Catalysis. The author has an hindex of 35, co-authored 105 publications receiving 3599 citations. Previous affiliations of Shiro Hikichi include Tokyo Institute of Technology & University of Tokyo.
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Journal ArticleDOI
Efficient Epoxidation of Olefins with ≥99% Selectivity and Use of Hydrogen Peroxide
TL;DR: The effectiveness of this catalyst is evidenced by ≥99% selectivity to epoxide, ≥ 99% efficiency of H2O2 utilization, high stereospecificity, and easy recovery of the catalyst from the homogeneous reaction mixture.
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Fixation of atmospheric carbon dioxide by a series of hydroxo complexes of divalent metal ions and the implication for the catalytic role of metal ion in carbonic anhydrase. Synthesis, characterization, and molecular structure of [LM(OH)]n (n = 1 or 2) and LM(.mu.-CO3)ML (M(II) = Mn, Fe, Co, Ni, Cu, Zn; L = HB(3,5-iso-Pr2pz)3)
TL;DR: In this article, a series of hydroxo complexes of first-row divalent metal ions (Mn (1), Fe (2), Co (3), Ni (4), Cu (5), Zn (6)) was synthesized.
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Synthesis and Structure Determination of Rh−diene Complexes with the Hydridotris(3,5-diisopropylpyrazolyl)borate Ligand, TpiPrRh(diene) (diene = cod, nbd): Dependence of the ν(B−H) Values on the Hapticity of the TpiPr Ligand (κ2 vs κ3)1
TL;DR: In this article, the B−H stretching vibrations of the square-planar and trigonal-bipyramidal structures of rh(μ-Cl) 2 with KTpiPr or TlTpiPr were identified.
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Olefin Epoxidation with Hydrogen Peroxide Catalyzed by Lacunary Polyoxometalate [γ‐SiW10O34(H2O)2]4−
TL;DR: The tetra-n-butylammonium (TBA) salt of the divacant Keggin-type polyoxometalate [TBA](4)[gamma-SiW(10)O(34)(H(2)O)(2)] catalyzes the oxygen-transfer reactions of olefins, allylic alcohols, and sulfides with 30 % aqueous hydrogen peroxide as mentioned in this paper.