S
Susan A. Nye
Researcher at Momentive
Publications - 21
Citations - 967
Susan A. Nye is an academic researcher from Momentive. The author has contributed to research in topics: Hydrosilylation & Cobalt. The author has an hindex of 10, co-authored 21 publications receiving 881 citations.
Papers
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Journal ArticleDOI
Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes
Aaron M. Tondreau,Crisita Carmen Hojilla Atienza,Keith J. Weller,Susan A. Nye,Kenrick M. Lewis,Johannes G.P. Delis,Paul J. Chirik +6 more
TL;DR: It is reported that well-characterized molecular iron coordination compounds promote the selective anti-Markovnikov addition of sterically hindered, tertiary silanes to alkenes under mild conditions, showing promise for industrial application.
Journal ArticleDOI
Bis(imino)pyridine Cobalt-Catalyzed Dehydrogenative Silylation of Alkenes: Scope, Mechanism, and Origins of Selective Allylsilane Formation
Crisita Carmen Hojilla Atienza,Tianning Diao,Keith J. Weller,Susan A. Nye,Kenrick M. Lewis,Johannes G.P. Delis,Julie L. Boyer,Aroop Kumar Roy,Paul J. Chirik +8 more
TL;DR: The aryl-substituted bis(imino)pyridine cobalt methyl complex, ((Mes)PDI)CoCH3), promotes the catalytic dehydrogenative silylation of linear α-olefins to selectively form the corresponding allylsilanes with commercially relevant tertiary silanes such as (Me3SiO)2MeSiH and (EtO)3SiH.
Journal ArticleDOI
Synthesis, Electronic Structure, and Alkene Hydrosilylation Activity of Terpyridine and Bis(imino)pyridine Iron Dialkyl Complexes
Aaron M. Tondreau,Crisita Carmen Hojilla Atienza,Jonathan M. Darmon,Carsten Milsmann,Helen M. Hoyt,Keith J. Weller,Susan A. Nye,Kenrick M. Lewis,Julie L. Boyer,Johannes G.P. Delis,Emil B. Lobkovsky,Paul J. Chirik +11 more
TL;DR: In this article, three different classes of tridentate, nitrogen-based, terpyridine, and pyridine bis(oxazoline) ligands have been synthesized and evaluated in the catalytic hydrosilylation of olefins with tertiary silanes.
Journal ArticleDOI
High-Selectivity Bis(imino)pyridine Iron Catalysts for the Hydrosilylation of 1,2,4-Trivinylcyclohexane
Crisita Carmen Hojilla Atienza,Aaron M. Tondreau,Keith J. Weller,Kenrick M. Lewis,Richard W. Cruse,Susan A. Nye,Julie L. Boyer,Johannes G.P. Delis,Paul J. Chirik +8 more
TL;DR: Aryl-substituted bis(imino)pyridine iron dinitrogen complexes are active for the hydrosilylation of 1,2,4-trivinylcyclohexane with tertiary alkoxy silanes, a process used in the manufacture of low rolling resistance tires as discussed by the authors.
Patent
In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts
Paul J. Chirik,Aaron M. Tondreau,Johannes G.P. Delis,Kenrick M. Lewis,Keith J. Weller,Susan A. Nye +5 more
TL;DR: In this article, a process for the hydrosilylation of a composition containing a silyl hydride and a compound containing at least one unsaturated group is described, the process comprising contacting a non-previous metal based complex as a catalyst precursor with an activator being a reducing agent.