T
Takashi Komuro
Researcher at Tohoku University
Publications - 47
Citations - 937
Takashi Komuro is an academic researcher from Tohoku University. The author has contributed to research in topics: Silylation & Ligand. The author has an hindex of 15, co-authored 44 publications receiving 785 citations. Previous affiliations of Takashi Komuro include Nagoya University.
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Journal ArticleDOI
A layered ionic crystal of polar Li@C 60 superatoms
Shinobu Aoyagi,Eiji Nishibori,Hiroshi Sawa,Kunihisa Sugimoto,Masaki Takata,Yasumitsu Miyata,Ryo Kitaura,Hisanori Shinohara,Hiroshi Okada,Takeshi Sakai,Yoshihiro Ono,Kazuhiko Kawachi,Kuniyoshi Yokoo,Shoichi Ono,Kenji Omote,Yasuhiko Kasama,Shinsuke Ishikawa,Takashi Komuro,Hiromi Tobita +18 more
TL;DR: The present method of purification and crystallization of C(60)-based metallofullerenes provides a new C( 60) fullerene material that contains a metal atom that has a unique two-dimensional structure.
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Preparation of endohedral fullerene containing lithium (Li@C60) and isolation as pure hexafluorophosphate salt ([Li+@C60][PF6−])
Hiroshi Okada,Hiroshi Okada,Takashi Komuro,Takeshi Sakai,Yutaka Matsuo,Yoshihiro Ono,Kenji Omote,Kuniyoshi Yokoo,Kazuhiko Kawachi,Yasuhiko Kasama,Shoichi Sendai-shi Ono,Rikizo Hatakeyama,Toshiro Kaneko,Hiromi Tobita +13 more
TL;DR: In this article, the synthesis, characterization, and properties of a chemically oxidized endohedral fullerene derivative [Li+@C60][PF6−] are reported in full, and an HPLC technique using an electrolyte in the mobile phase is effective in purifying the ionic metallofullerene.
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Synthesis and reactions of triphenylsilanethiolato complexes of manganese(II), iron(II), cobalt(II), and nickel(II).
TL;DR: The silanethiolato complexes reported here are expected to serve as convenient precursors for sulfido cluster synthesis.
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Coordination chemistry of silanedithiolato ligands derived from cyclotrisilathiane: synthesis and structures of complexes of iron(II), cobalt(II), palladium(II), copper(I), and silver(I).
TL;DR: The chelating effect of silanedithiolato ligands leads to an increase in the stability of silylated thiolato complexes.
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Double and Single Hydroboration of Nitriles Catalyzed by a Ruthenium-Bis(silyl)xanthene Complex: Application to One-Pot Synthesis of Diarylamines and N-Arylimines
TL;DR: A ruthenium complex bearing a bis(silyl)xanthene chelate ligand xantsil was found to catalyze both double and single hydroboration reactions of nitriles with pinacolborane (HBpin) and 9-borabicyclo[3.3.1]nonane (9-BBN) to give bis(boryl)amines 2 and N-borylimines 3, respectively, in mostly >99% yields.