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Thomas Bally

Researcher at University of Fribourg

Publications -  171
Citations -  4296

Thomas Bally is an academic researcher from University of Fribourg. The author has contributed to research in topics: Radical ion & Excited state. The author has an hindex of 34, co-authored 171 publications receiving 4086 citations. Previous affiliations of Thomas Bally include University of Queensland & University of Wisconsin-Madison.

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Journal ArticleDOI

The c8h8 radical cations of cyclooctatetraene, semibullvalene, and their common bisallylic rearrangement product : electronic structure and potential energy surfaces

TL;DR: In this article, the electronic and molecular structure of BOD{sup+} and its photoprecursor, the radical cation of cyclooctatetraene (COT{sup +}), are discussed on the basis of their EA spectra and ab initio calculations.
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Mechanistic Aspects of the Oxidative and Reductive Fragmentation of N-Nitrosoamines: A New Method for Generating Nitrenium Cations, Amide Anions, and Aminyl Radicals

TL;DR: A new method for investigating the mechanisms of nitric oxide release from NO donors under oxidative and reductive conditions is presented and should prove generally applicable to the generation and study of nitrenium cations and amide anions R2N+/- under matrix and ambient conditions.
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Electronic Structure and Absorption Spectra of Biferrocenyl and Bisfulvalenide Diiron Radical Cations: Detection and Assignment of New Low‐Energy Transitions

TL;DR: UV-visible/near-IR (NIR/mid-IR) solution, solid-state, and matrix-isolation electronic absorption spectra of the Fe(II)-Fe(III) mixed-valent homobimetallic compounds biferrocenyl triiodide and 1',1'''-diethylbiferrocenyltriiodide reveal the presence of a low-energy transition in the MIR region that has not been reported before.
Book ChapterDOI

Electronic Structure, Spectroscopy, and Photochemistry of Organic Radical Cations

TL;DR: Although the concept of one-electron oxidation or reduction in condensed phase did not gain general acceptance until the 1930's when the advent of electrochemical techniques made it possible to lend direct experimental proof to this notion, radical ions (henceforth abbreviated as M+/M−) had aroused the interest of chemists much earlier.
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Light induced processes in organic molecular ions

TL;DR: A short review of the current state of knowledge about Mt-photoprocesses and some pertinent photophysical parameters of Mt used to rationalize these reactions can be found in this article.