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Vincent Aubert

Researcher at University of Rennes

Publications -  9
Citations -  442

Vincent Aubert is an academic researcher from University of Rennes. The author has contributed to research in topics: Bipyridine & Catalysis. The author has an hindex of 7, co-authored 9 publications receiving 421 citations.

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Linear and nonlinear optical properties of cationic bipyridyl iridium(III) complexes: tunable and photoswitchable?

TL;DR: High negative EFISH μβ values are observed upon photocyclization, suggesting that the quadratic NLO response is dominated by the MLCT/L'LCT processes, rather than by the intraligand excited states localized on the substituted bipyridine ligand.
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Selective ruthenium-catalyzed transformations of enynes with diazoalkanes into alkenylbicyclo[3.1.0]hexanes.

TL;DR: Density functional theory calculations performed starting from the model system Ru(HCCH)(CH2=CH2)Cl(C5H5) show that the transformation into a ruthenacyclobutane intermediate occurs with a temporary eta3-coordination of the cyclopentadienyl ligand.
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The first hexadithienylethene-substituted tris(bipyridine)metal complexes as quadratic NLO photoswitches: combined experimental and DFT studies.

TL;DR: The photostability of the isomeric forms of the iron(II) complexes allows the photoswitching of second-order nonlinear optical (NLO) responses, and the results are rationalized with the help of time-dependent density functional theory.
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A “reverse interrupter”: the novel molecular design of a fluorescent photochromic DTE-based bipyridine

TL;DR: An original design of a fluorescent dithienylethene (DTE)-based bipyridine, where donor (D) and acceptor (A) groups are located on the same thiophene ring of the DTE unit, is reported in this paper.