The interest in nanoscale materials stems from the fact that new properties are acquired at this length scale and, equally important, that these properties * To whom correspondence should be addressed. Phone, 404-8940292; fax, 404-894-0294; e-mail, mostafa.el-sayed@ chemistry.gatech.edu. † Case Western Reserve UniversitysMillis 2258. ‡ Phone, 216-368-5918; fax, 216-368-3006; e-mail, burda@case.edu. § Georgia Institute of Technology. 1025 Chem. Rev. 2005, 105, 1025−1102

Chemistry and properties of nanocrystals of different shapes.

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Principles Of Fluorescence Spectroscopy

The surface and materials science of tin oxide

Solution-processed optoelectronic and electronic devices are attractive owing to the potential for low-cost fabrication of large-area devices and the compatibility with lightweight, flexible plastic substrates. Solution-processed light-emitting diodes (LEDs) using conjugated polymers or quantum dots as emitters have attracted great interest over the past two decades. However, the overall performance of solution-processed LEDs--including their efficiency, efficiency roll-off at high current densities, turn-on voltage and lifetime under operational conditions-remains inferior to that of the best vacuum-deposited organic LEDs. Here we report a solution-processed, multilayer quantum-dot-based LED with excellent performance and reproducibility. It exhibits colour-saturated deep-red emission, sub-bandgap turn-on at 1.7 volts, high external quantum efficiencies of up to 20.5 per cent, low efficiency roll-off (up to 15.1 per cent of the external quantum efficiency at 100 mA cm(-2)), and a long operational lifetime of more than 100,000 hours at 100 cd m(-2), making this device the best-performing solution-processed red LED so far, comparable to state-of-the-art vacuum-deposited organic LEDs. This optoelectronic performance is achieved by inserting an insulating layer between the quantum dot layer and the oxide electron-transport layer to optimize charge balance in the device and preserve the superior emissive properties of the quantum dots. We anticipate that our results will be a starting point for further research, leading to high-performance, all-solution-processed quantum-dot-based LEDs ideal for next-generation display and solid-state lighting technologies.

Solution-processed, high-performance light-emitting diodes based on quantum dots

Recently, Kovalenko and co-workers and Li and co-workers developed CsPbX3 (X = Cl, Br, I) inorganic perovskite quantum dots (IPQDs), which exhibited ultrahigh photoluminescence (PL) quantum yields (QYs), low-threshold lasing, and multicolor electroluminescence. However, the usual synthesis needs high temperature, inert gas protection, and localized injection operation, which are severely against applications. Moreover, the so unexpectedly high QYs are very confusing. Here, for the first time, the IPQDs' room-temperature (RT) synthesis, superior PL, underlying origins and potentials in lighting and displays are reported. The synthesis is designed according to supersaturated recrystallization (SR), which is operated at RT, within few seconds, free from inert gas and injection operation. Although formed at RT, IPQDs' PLs have QYs of 80%, 95%, 70%, and FWHMs of 35, 20, and 18 nm for red, green, and blue emissions. As to the origins, the observed 40 meV exciton binding energy, halogen self-passivation effect, and CsPbX3@X quantum-well band alignment are proposed to guarantee the excitons generation and high-rate radiative recombination at RT. Moreover, such superior optical merits endow them with promising potentials in lighting and displays, which are primarily demonstrated by the white light-emitting diodes with tunable color temperature and wide color gamut.

CsPbX3 Quantum Dots for Lighting and Displays: Room-Temperature Synthesis, Photoluminescence Superiorities, Underlying Origins and White Light-Emitting Diodes

The monitoring of proximity-contact events is essential for human-machine interactions, intelligent robots, and healthcare monitoring. We report a dual-modal sensor made with two functionalized optical microfibers (MFs), which is inspired by the somatosensory system of human skin. The integrated sensor with a hierarchical structure gradationally detects finger approaching and touching by measuring the relative humidity (RH) and force-triggered light intensity variations. Specifically, the RH sensory part shows enhanced evanescent absorption, achieving a sensitive RH measurement with a fast response (110 ms), a high resolution (0.11%RH), and a wide working range (10-100%RH). Enabled by the transition from guided modes into radiation modes of the waveguiding MF, the force sensory part exhibits a high sensitivity (6.2%/kPa) and a fast response (up to 1.5 kHz). By using a real-time data processing unit, the proximity-contact sensor (PCS) achieves continuous detection of the full-contact events, including finger approaching, contacting, pressing, releasing, and leaving. As a proof of concept, the electromagnetic-interference-free PCS enables a smart switch system to recognize the proximity and contact of bare/gloved fingers. Moreover, skin humidity detection and respiration monitoring are realized. These initial results pave the way toward a category of optical collaborative devices ranging from human-machine interfaces to multifunctional on-skin healthcare sensors.

Optical Microfibers for Sensing Proximity and Contact in Human-Machine Interfaces.

Fast Lasing Wavelength Tuning in Single Nanowires

Laser based on single plasmonic nanoparticle can provide optical frequency radiation far beyond the diffraction limit and is one of the ultimate goals of nanolasers, yet it remains a challenge to be realized because of the inherently high Ohmic loss. Here, we report the direct observation of lasing in microfiber-coupled single plasmonic nanoparticles enabled by strong mode coupling. We show that, by strongly coupling a gold nanorod (GNR) with the whispering gallery cavity of a dye-doped polymer microfiber (with diameter down to 2.0 μm), the substantially enhanced optical coherence of the hybrid photon-plasmon mode and effective gain accumulated from the active microfiber cavity enable single-mode laser emission from the GNR at room temperature with a threshold as low as 2.71 MW/cm2 and a linewidth narrower than 2 nm.

Strong mode coupling-enabled hybrid photon-plasmon laser with a microfiber-coupled nanorod

We demonstrate a novel optofluidic refractive index (RI) sensor with high sensitivity and wide dynamic range based on partial reflection. Benefited from the divergent incident light and the output fibers with different tilting angles, we have achieved highly sensitive RI sensing in a wide range from 1.33 to 1.37. To investigate the effectiveness of this sensor, we perform a measurement of RI with a resolution of ca. 5.0×10–5 refractive index unit (RIU) for ethylene glycol solutions. Also, we have measured a series of liquid solutions by using different output fibers, achieving a resolution of ca. 0.52 mg/mL for cane surge. The optofluidic RI sensor takes advantage of the high sensitivity, wide dynamic range, small footprint, and low sample consumption, as well as the efficient fluidic sample delivery, making it useful for applications in the food industry.

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Optofluidic refractive index sensor based on partial reflection

Single-mode fiber coupler with variable coupling ratio is a flexible tool for optical fiber applications. Here we demonstrate a microfiber based coupler with compact size and wide tuning range. The coupler consists of two identical single-mode microfibers that are fabricated via parallel pulling process. By adjusting the twisting angle between these microfibers, the coupling ratio varies from 3.15% to 98.5% due to the change of evanescent field interaction length. Numerical simulations are carried out and the results agree well with the experimental ones. The effects of diameter discrepancy between two microfibers and mode polarization are also studied experimentally and numerically.

Wei Fang

Papers

Optical Microfibers for Sensing Proximity and Contact in Human-Machine Interfaces.

Fast Lasing Wavelength Tuning in Single Nanowires

Strong mode coupling-enabled hybrid photon-plasmon laser with a microfiber-coupled nanorod

Optofluidic refractive index sensor based on partial reflection

Experimental Demonstration of a Compact Variable Single-Mode Fiber Coupler Based on Microfiber