A common misconception is that the irradiation of solids with energetic electrons and ions has exclusively detrimental effects on the properties of target materials. In addition to the well-known cases of doping of bulk semiconductors and ion beam nitriding of steels, recent experiments show that irradiation can also have beneficial effects on nanostructured systems. Electron or ion beams may serve as tools to synthesize nanoclusters and nanowires, change their morphology in a controllable manner, and tailor their mechanical, electronic, and even magnetic properties. Harnessing irradiation as a tool for modifying material properties at the nanoscale requires having the full microscopic picture of defect production and annealing in nanotargets. In this article, we review recent progress in the understanding of effects of irradiation on various zero-dimensional and one-dimensional nanoscale systems, such as semiconductor and metal nanoclusters and nanowires, nanotubes, and fullerenes. We also consider the t...

Ion and electron irradiation-induced effects in nanostructured materials

Laser ablation in liquids : Applications in the synthesis of nanocrystals

Irradiating solids with energetic particles is usually thought to introduce disorder, normally an undesirable phenomenon. But recent experiments on electron or ion irradiation of various nanostructures demonstrate that it can have beneficial effects and that electron or ion beams may be used to tailor the structure and properties of nanosystems with high precision. Moreover, in many cases irradiation can lead to self-organization or self-assembly in nanostructures. In this review we survey recent advances in the rapidly evolving area of irradiation effects in nanostructured materials, with particular emphasis on carbon systems because of their technological importance and the unique ability of graphitic networks to reconstruct under irradiation. We dwell not only on the physics behind irradiation of nanostructures but also on the technical applicability of irradiation for nanoengineering of carbon and other systems.

Engineering of nanostructured carbon materials with electron or ion beams

We exploited the exceptional thermal stability and diverse molecular shapes of higher diamondoids (C22 and higher polymantanes) to isolate them from petroleum. Molecules containing 4 to 11 diamond-crystal cages were isolated and crystallized, and we obtained single-crystal x-ray structures for representatives from three families. Rigidity, strength, remarkable assortments of three- dimensional shapes, including resolvable chiral forms, and multiple, readily derivatizable attachment sites make them valuable nanometer-size molecular building blocks.

https://science.sciencemag.org/content/sci/299/5603/96.full.pdf

Isolation and structure of higher diamondoids, nanometer-sized diamond molecules.

The unique plasma-specific features and physical phenomena in the organization of nanoscale soild-state systems in a broad range of elemental composition, structure, and dimensionality are critically reviewed. These effects lead to the possibility to localize and control energy and matter at nanoscales and to produce self-organized nano-solids with highly unusual and superior properties. A unifying conceptual framework based on the control of production, transport, and self-organization of precursor species is introduced and a variety of plasma-specific non-equilibrium and kinetics-driven phenomena across the many temporal and spatial scales is explained. When the plasma is localized to micrometer and nanometer dimensions, new emergent phenomena arise. The examples range from semiconducting quantum dots and nanowires, chirality control of single-walled carbon nanotubes, ultra-fine manipulation of graphenes, nano-diamond, and organic matter to nano-plasma effects and nano-plasmas of different states of matter.

Plasma nanoscience: from nano-solids in plasmas to nano-plasmas in solids

A model for diamond nucleation by energetic species (for example, bias-enhanced nucleation) is proposed. It involves spontaneous bulk nucleation of a diamond embryo cluster in a dense, amorphous carbon hydrogenated matrix; stabilization of the cluster by favorable boundary conditions of nucleation sites and hydrogen termination; and ion bombardment-induced growth through a preferential displacement mechanism. The model is substantiated by density functional tight-binding molecular dynamics simulations and an experimental study of the structure of bias-enhanced and ion beam-nucleated films. The model is also applicable to the nucleation of other materials by energetic species, such as cubic boron nitride.

http://science.sciencemag.org/content/sci/297/5586/1531.full.pdf

The mechanism of diamond nucleation from energetic species.

A diamond nucleation site responsible for epitaxial growth of diamond on silicon by chemical vapor deposition (CVD) is identified in high-resolution transmission electron microscopic images. Other sites in the same sample leading to polycrystalline growth, but deleterious to epitaxial CVD growth, are also described. A mechanism for the heteroepitaxial growth of diamond is suggested, in which etching of the nondiamond carbon binder exposes and removes nonadherent nanodiamond nuclei, leaving intact only those directly nucleated on the silicon substrate. This work enhances our understanding of diamond nucleation and heteroepitaxial growth and its potential applications.

http://staff.ustc.edu.cn/~fuzp/course/paper/A%20Nucleation%20Site%20and%20Mechanism%20Leading%20to%20Epitaxial%20Growth%20of%20Diamond%20Films.pdf

X. T. Zhou

Papers

The mechanism of diamond nucleation from energetic species.

A Nucleation Site and Mechanism Leading to Epitaxial Growth of Diamond Films

Formation and structure of a-C/nanodiamond composite films by prolonged bias enhanced nucleation

Epitaxial growth of β-SiC on Si (100) by low energy ion beam deposition