Yuushi Shimoda

TL;DR: The kinetics of the photochemical formation processes of the one-electron-reduced species RuC2(Re)−, which is an essential intermediate in the photocatalytic reaction, were clarified in detail and its electronic structure was elucidated.

TL;DR: It is uncovered that the structural restriction of the intramolecular flexibility significantly affects the optimized geometry and phonon modes coupled to the spin conversion, providing a microscopic strategy to control the optoelectronic properties from a molecular viewpoint.

TL;DR: A ReV complex demonstrates methanol selective luminescent color changes from red to green together with enhancements of the corresponding luminescence quantum yields twenty-three times.

TL;DR: In this article, structural factors on photophysical properties in two rhenium(I) diimine complexes in acetonitrile solution were explored, and it was concluded that the instability from steric effects of phenyl groups and diimines leads to a smaller Stokes shift of the lowest excited triplet state (T1) in (3,3).

TL;DR: In this article, the excited state energy was tuned successfully by guest molecules in a cyanide-bridged luminescent coordination polymer (CP), which showed that solvent adsorption enhanced the energetic relaxation in the excited states.