Spectral Sciences Incorporated

About: Spectral Sciences Incorporated is a company organization based out in Burlington, Massachusetts, United States. It is known for research contribution in the topics: Hyperspectral imaging & Radiance. The organization has 114 authors who have published 342 publications receiving 10875 citations.

Ultraviolet absorption hygrometer

Abstract: An ultraviolet absorption hygrometer is provided including a source of pulsed ultraviolet radiation for providing radiation in a first wavelength region where water absorbs significantly and in a second proximate wavelength region where water absorbs weakly. Ultraviolet radiation in the first and second regions which has been transmitted through a sample path of atmosphere is detected. The intensity of the radiation transmitted in each of the first and second regions is compared and from this comparison the amount of water in the sample path is determined.

Infrared species specific emission source

Abstract: An infrared species specific emission source which includes a closed container having at least one transparent portion for containing at least one specific molecular species. The molecular species within the container is heated sufficiently to cause the species to emit a characteristic infrared spectal emission through the at least one transparent portion of the container to the infrared instrument.

Fast Monte Carlo full spectrum scene simulation

Abstract: This paper discusses the formulation and implementation of an acceleration approach for the MCScene code, a high fidelity model for full optical spectrum (UV to LWIR) hyperspectral image (HSI) simulation. The MCScene simulation is based on a Direct Simulation Monte Carlo approach for modeling 3D atmospheric radiative transport, as well as spatially inhomogeneous surfaces including surface BRDF effects. The model includes treatment of land and ocean surfaces, 3D terrain, 3D surface objects, and effects of finite clouds with surface shadowing. This paper will review an acceleration algorithm that exploits spectral redundancies in hyperspectral images. In this algorithm, the full scene is determined for a subset of spectral channels, and then this multispectral scene is unmixed into spectral end members and end member abundance maps. Next, pure end member pixels are determined at their full hyperspectral resolution, and the full hyperspectral scene is reconstructed from the hyperspectral end member spectra and the multispectral abundance maps. This algorithm effectively performs a hyperspectral simulation while requiring only the computational time of a multispectral simulation. The acceleration algorithm will be demonstrated, and errors associated with the algorithm will be analyzed.

Measurements and simulations of high energy O(3P) + Ar(1S) angular scattering: single and multi-collision regimes.

Abstract: We present differential angular cross sections for O(3P)+Ar(1S) scattering at collision energies near 90 kcal mol−1 (∼8 km s−1 relative velocity) from molecular beam measurements and high-level theoretical calculations Beams of hyperthermal O(3P) are now being used to investigate novel gas-phase and gas-surface chemistries, and the comparison of theory and measurements on this simple system will be a stringent test of the experimental methodology Potential energy curves were generated for O(3P)+Ar(1S) using a large cc-pVQZ basis within a valence multi-configuration plus perturbation theory treatment These curves were then used in quantum scattering calculations to generate differential cross sections Agreement between experiment and theory is excellent In addition to these comparisons, the cross sections were used in direct simulation Monte Carlo calculations to investigate effects of increasing the Ar flux above the “single-collision” regime As the Ar flux increases, the observed differential angul

On estimating interstellar polycyclic aromatic hydrocarbon abundances with calculated oscillator strengths

Abstract: Vibronic bands of polycyclic aromatic hydrocarbons (PAHs) in the UV/visible range are often used to estimate the abundances of PAHs in the interstellar medium by comparing laboratory-measured spectra with astronomical observations. We investigate the errors introduced by associating theoretical electronic oscillator strengths with individual vibronic bands when estimating the abundances of interstellar PAHs. The vibronic oscillator strengths of the 0-0 bands of nine PAHs with two to seven benzene rings, spanning in the 2800-6700 A spectral range, have been calculated using the Franck-Condon approximation and compared to their electronic oscillator strengths. It is found that the use of calculated electronic oscillator strengths rather than the more physically relevant vibronic oscillator strengths underestimates interstellar abundances of the nine PAHs under study, on average by a factor of about 2.4. It is recommended that vibronic oscillator strengths should be systematically used to analyze the vibronic spectra of specific PAHs and to estimate their abundances in the interstellar medium. An empirical correcting factor is suggested for the cases where the vibronic oscillator strengths are unknown for more realistic estimation of interstellar PAH abundances.