Showing papers in "Journal of Electron Spectroscopy and Related Phenomena in 1985"

TL;DR: In this paper, the surfaces of lithium and barium sulfates and carbonates under 4 ke V Ar + bombardment were investigated by X-ray photoelectron spectroscopy (XPS).

TL;DR: Least-squares fitting with a mathematical model function provides the most effective technique for extracting numerical information from photoemission data as mentioned in this paper, and the validity of a model function can be judged by inspection of the spectrum of the residuals.

TL;DR: In this paper, the 4 f core-level X-ray photoemission of small Pt clusters deposited on Teflon and SiO 2 substrates has been investigated and the experimental results are discussed and related to other data reported in the literature.

TL;DR: In this paper, it was shown that the final state relaxation contribution Δ R (P 2 p ) of the binding energy shift Δ E B (i) is determined by coulomb contributions.

TL;DR: A discussion of factors related to improved resolution in electron Spectroscopy for different modes of excitation is given and some examples are presented from recent studies of solids, gases and liquids, together with some aspects on angular distributions.

TL;DR: In this article, the reduction sequence of intrazeolite Cu(II), Cu(I), Cu clusters and externally segregated copper metal crystallites was analyzed under reducing conditions (CO, H 2, 250-450° C).

TL;DR: A complete set of electron-excited 4 d -basedAuger spectra of the lanthanide metals from lanthanum to lutetium (except the unstable promethium) is presented, in both differential and integral forms as mentioned in this paper.

TL;DR: In this paper, the inner-shell spectra of (CH3)3N and NH3 are compared with the reported valence-shell optical absorption spectra and support the Rydberg assignment.

TL;DR: In this article, a hemispherical analyzer is used for multichannel detection with high spatial resolution position sensitive devices for multi-channel detection, and criteria are established for optimizing detection efficiency, choosing various parameters and analyzing effects of fringing electric fields and magnetic fields on analyzer performance.

TL;DR: In this article, the effect of elastic electron scattering on the asymmetry parameter β was quantified for photoelectrons with kinetic energies within 1.5 keV and elements up to Z = 46.

TL;DR: In this paper, the inner shell excitation spectra of tetramethylsilane, (CH 3 ) 4 Si, have been measured in the silicon 2 s, 2 p (L I,II,III -shell) and carbon is (K)-shell regions using electron energy-loss spectroscopy at an impact energy of 2.5 keV and a scattering angle of ~1°.

TL;DR: In this article, the inner shell electronic excitation spectra of PH3, PF3, PCl3 and P(CH3)3 were obtained under small momentum transfer conditions so that dipole-allowed transitions dominate.

TL;DR: In this paper, the results of experiments on low energy electrons passing through thin amorphous carbon films are reported and the electron attenuation length for inelastic scattering was found to increase monotonically from approximately 10 to 55 A over the 50 to 3000 eV range.

TL;DR: In this article, a set of calculations using a developed extension of the self-consistent field- X α scattered-wave method to the continuum states were compared to a comparison between the experimental and calculated β curves of the outer and the inner valence shells of H 2 S.

TL;DR: In this paper, a monochromated Ag Lα (linewidth 1.3 eV) XPS source is presented for a high energy XPS (HESA 3 Mk. II) transmission function up to 3000 eV.

TL;DR: In this article, a variable angle photoelectron spectrometer utilizing a position-sensitive multidetector is described, and the data are acquired using a new technique in which the photo electron yield is obtained as a function of both wavelength and photo electron energy, which gives detailed information on autoionization processes.

TL;DR: Experimental AES and XPS results from powdered α-Al2O3, SiO2, Al2Si2O7·2H2O and an aluminosilicate glass are presented as qualitative reference data for the purpose of aiding in the identification of unknown aluminum oxide/silicon oxide samples.

TL;DR: In this paper, the inner shell electron energy loss spectra of trans-1,3-butadiene and allene are presented, and the transition to both π * and π→π * levels in trans -1, 3 butadiene are clearly identified.

TL;DR: In this article, the X α scattered wave method was used to calculate the K β/K α X-ray intensity ratio for some manganese and chromium compounds, which varies from 1.2 to 3.6% for different compounds.

TL;DR: In this paper, the electron-ion coincidence spectra of chlorofluoromethanes obtained after He(I)-photoionization and Penning ionization by He(2 3 S ).

TL;DR: In this paper, X-ray photoemission spectroscopy (XPS) results have given a direct insight into the surface composition of Fe-Al 2 O 3 “granular” thin films consisting of fine iron particles (φ ~ 40-150 A) dispersed in an insulating alumina matrix.

TL;DR: Etude de la liaison avec la surface du carbonate forme par reaction du dioxyde de carbone avec de l'oxygene preadsorbe as discussed by the authors.

TL;DR: Relative intensities for the photoelectron reaction on atoms and molecules are not related to structure calculations in the same way as those for the noncoplanar symmetric (e, 2e) reaction as discussed by the authors.

TL;DR: In this article, the angular distribution of the uppermost π-band (1 e 1g ) of polystyrene was analyzed and shown to have a β parameter of β = 0.6 for hν = 31 eV.

TL;DR: In this article, a semi-empirical equation is presented which may be used to calculate the relative sensitivities of the elements for Auger electron spectroscopic analysis, which involves the product of a large number of theoretically or empirically derived terms, including ionization cross section.