4-Aminopyridinium cis-2-carboxycyclohexane-1-carboxylate
Graham Smith,Urs D. Wermuth +1 more
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TLDR
In the structure of the title molecular salt, C5H7N2 +·C8H11O4 −, the cis monoanions associate through short O—H⋯O hydrogen bonds in the carboxylic acid groups, forming zigzag chains which extend along the c axis.Abstract:
In the structure of the title compound, C5H7N2+·C8H11O4−, the cis anions associate through head-to-tail carboxylic acid–carboxyl O—H⋯O hydrogen bonds [graph set C(7)], forming chains which extend along c and are interlinked through the carboxyl groups, forming cyclic R22(8) associations with the pyridinium and an amine H-atom donor of the cation. Further amine–carboxyl N—H⋯O interactions form enlarged centrosymmetric rings [graph set R44(18)] and extensions down b, giving a three-dimensional structure.read more
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Investigations on Structural, Mechanical, Optical, Electrical, Third-Order Nonlinear Optical and Antibacterial Activity of 4-Aminopyridine Monophthalate Single Crystal
S. Sakthy Priya,Kaushik Balakrishnan,P. Surendran,A. Lakshmanan,P. Geetha,P. Rameshkumar,Tejaswi Ashok Hegde,G. Vinitha,A. Antony Raj +8 more
TL;DR: In this article, an organic 4aminopyridine monophthalate (PA4AP) single crystal grown by solvent evaporation at room temperature was studied for third-order nonlinear optical and antibacterial applications.
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1-(7-chloro-1,4-dihydroquinolin-4-ylidene)thiosemicarbazide and its hydrochloride: evidence for the existence of a stable imine tautomer in the solid state of 4-aminoquinoline free bases, an anomalous case in nitrogen heterocycles.
TL;DR: The crystal structures of (I) and (II) in this study provide interesting examples of the amino-imino tautomerism which exists in this class of compound and is, to the best of the authors' knowledge, hitherto unreported.
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Synthesis, Crystal Structure, and Free Radical Scavenging Activity of 4-Aminopyridinium 3,5-Dinitrobenzoate
TL;DR: The crystal structure of 4-aminopyridinium 3,5-dinitrobenzoate, C12H10O6N4, has been determined by single-crystal X-ray diffraction technique.
References
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TL;DR: This paper reports on the current status of structure validation in chemical crystallography and describes the current state of research in this area.
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