Journal ArticleDOI
A convenient synthesis of α-D-glucopyranosides
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This article is published in Synthesis.The article was published on 1988-01-01. It has received 20 citations till now. The article focuses on the topics: Aldose & Nuclear magnetic resonance spectroscopy.read more
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Journal ArticleDOI
Borinic Acid Catalyzed Stereo- and Regioselective Couplings of Glycosyl Methanesulfonates.
Kyan A. D’Angelo,Mark S. Taylor +1 more
TL;DR: The results suggest that although the uncatalyzed and catalyzed reactions give rise to opposite stereochemical outcomes, both proceed by associative mechanisms.
Journal ArticleDOI
CHEMISTRY OF GLYCOSYL TRIFLATES: SYNTHESIS OF β-MANNOPYRANOSIDES
TL;DR: Among the numerous and varied glycosyl donors known, the sulfonates have been somewhat neglected in recent years, despite their considerable potential in stereoselective glycolyation as discussed by the authors.
Journal ArticleDOI
Cytostatic and cytotoxic activity of synthetic genistein glycosides against human cancer cell lines.
Krzysztof Polkowski,Joanna Popiołkiewicz,Piotr Krzeczyński,Jan Ramza,Wiesław Pucko,Oliwia Zegrocka-Stendel,Jerzy Boryski,Janusz Skierski,Aleksander P. Mazurek,Grzegorz Grynkiewicz +9 more
TL;DR: All lipophilic glycosides were revealed to exhibit different mode of action in comparison to genistein, which may suggest that these compounds do not undergo rapid biodegradation, either in culture media or inside cells, and exert their biological effects primarily as intact molecules.
Journal ArticleDOI
One-Pot α-Glycosylation Method Using Appel Agents in N,N-Dimethylformamide
TL;DR: In this article, a concept for the development of practical glycosylation is presented and demonstrated by one-pot α-glycosylations applying Appel agents for 2-O-benzyl-1-OH hexoses in DMF.
Journal ArticleDOI
Dehydrative glycosylation with 1-hydroxy donors
TL;DR: The preparation of complex carbohydrates has emerged as a major focus in synthetic organic chemistry, and this is no doubt a result of the growing awareness of the many important roles of this clas... as mentioned in this paper.
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Synthesis of glycosyl halides and glycosides via 1-O-sulfonyl derivatives
Jacques Leroux,Arthur S. Perlin +1 more