Journal ArticleDOI
A semi-empirical method of absorption correction
TLDR
An extension of Furnas's method is described in this paper, where the variation of intensity of an axial reflection as the crystal is rotated about the goniometer axis is used to give a curve of relative transmission T against azimuthal angle ϕ for the corresponding reciprocal lattice level.Abstract:
An extension of Furnas's method is described. The variation of intensity of an axial reflection as the crystal is rotated about the goniometer axis is used to give a curve of relative transmission T against azimuthal angle ϕ for the corresponding reciprocal lattice level. Transmission coefficients for any general reflexion hkl are then given approximately by T(hkl) = [T(ϕinc) + T(ϕret)]/2 where ϕinc and ϕret are the azimuthal angles of the incident and reflected beams. Equations are derived for (ϕinc and ϕret and the accuracy of the method is discussed.read more
Citations
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Journal ArticleDOI
The three-dimensional structure of mitochondrial aspartate aminotransferase at 4.5 Å resolution
Gregor Eichele,Geoffrey C. Ford,Martin Glor,Johan N. Jansonius,Charalampos Mavrides,Philipp Christen +5 more
TL;DR: An X-ray crystallographic study at 4.5 A resolution has been carried out with triclinic crystals of chicken mitochondrial aspartate aminotransferase, revealing the positions of the pyridoxyl and the phosphate moieties of the coenzyme as well as the general substrate binding area.
Journal ArticleDOI
Investigation on growth, structure and characterization of succinate salt of 8-hydroxyquinoline: an organic NLO crystal.
TL;DR: The structure of the grown crystal has been elucidated by single crystal X-ray diffraction analysis and it reveals that 8-HQSU crystallizes in monoclinic system with non-centro symmetric space group P2(1).
Journal ArticleDOI
Palladium(II) and platinum(II)-C(3)-substituted 2,2′-bipyridines
Giovanni Minghetti,Angelino Doppiu,Antonio Zucca,Sergio Stoccoro,Maria Agostina Cinellu,Mario Manassero,Mirella Sansoni +6 more
TL;DR: In this paper, the reaction of Pd(OAc)2 with HL1 and HL2 (HL1=6-iso-propyl-2,2′-bipyridine; HL2=6neo-pentyl- 2,2.2′)-bipryridine, followed by treatment with LiCl or KI, gives [PdCl(L1)]2, (1), [PdrCl(l2)]2 (2), and [PrCl(I(L2))2, respectively.
Journal ArticleDOI
The structure of a rhombohedral R6 insulin hexamer that binds phenol.
G. D. Smith,Guy Dodson +1 more
TL;DR: The structure has been solved and refined, using data between 8.0 and 2.5 Å resolution, and an elliptical cavity is created between symmetry–related monomers and is occupied by a phenol molecule.
Journal ArticleDOI
Efficient Synthesis of Ruthenium(II) η5-Dienyl Compounds Starting from Di-μ-chlorodichloro- bis[(1−3η:6−8η)-2,7-dimethyloctadienediyl]diruthenium(IV). Versatile Precursors for Enantioselective Hydrogenation Catalysts
TL;DR: In this paper, the dimeric complex di-μ-chlorodichloro-bis[(1−3η:6−8η)-2,7-dimethyl octadienediyl]diruthenium(IV) in the presence of base reacts with cyclic and acyclic dienes to the corresponding bis(η5-dienyl)rutheniam(II) compounds.
References
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Book
International tables for X-ray crystallography
Norman Fordyce McKerron Henry,Lonsdale, Kathleen, Dame,John S. Kasper,Caroline H. MacGillavry,Gerard D. Rieck,James A. Ibers,Walter C. Hamilton +6 more
ReportDOI
A fortran program for calculating single crystal absorption corrections
D.J. Wehe,W.R. Busing,H.A. Levy +2 more
TL;DR: A Fortran program is described for calculating the absorption correction for application to single crystal x ray or neutron intensity measurements and is available in the form of symbolic punched cards.