Journal ArticleDOI
A study of the electrodeposition and subsequent potential cycling of Prussian Blue films using ellipsometry
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This article is published in Journal of Electroanalytical Chemistry.The article was published on 1988-11-10. It has received 52 citations till now. The article focuses on the topics: Prussian blue & Ellipsometry.read more
Citations
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Beneficial role of surfactants in electrochemistry and in the modification of electrodes
TL;DR: The article gives a brief account on metal hexacyanoferrate modified electrodes and the salient features of the published results on the beneficial role of cetyltrimethylammonium bromide (CTAB), a cationic surfactant, in the modification of electrodes with MHCFs and their derivatized oxides, and with titanium dioxide.
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Electrochemical Charging, Countercation Accommodation, and Spectrochemical Identity of Microcrystalline Solid Cobalt Hexacyanoferrate
Pawel J. Kulesza,Marcin A. Malik,Mario Berrettoni,Marco Giorgetti,Silvia Zamponi,Roman Schmidt,Roberto Marassi +6 more
TL;DR: In this article, Oxidized and reduced cobalt(II) hexacyanoferrates were fabricated and characterized in the presence of alkali metal (Li+, Na+, K+, Cs+) and Co2+ countercations.
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In Situ FT-IR/ATR Spectroelectrochemistry of Prussian Blue in the Solid State
TL;DR: In this paper, the combination of electrochemistry in the absence of liquid electrolyte with internal reflectance FT-IR spectroscopy was accomplished using a simple two-electrode sandwich-type cell in which a crystalline germanium served both as a working electrode and an infrared transparent element.
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Lattice contractions and expansions accompanying the electrochemical conversions of Prussian blue and the reversible and irreversible insertion of rubidium and thallium ions
TL;DR: In this paper, a model of the lattice contraction and expansion of the Prussian blue lattice was proposed to explain the irreversible binding of one of the Rb+ and Tl+ cations.
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Electroanalysis with electrodes modified by inorganic films
TL;DR: The electroanalytical utility of electrodes modified with inorganic films is reviewed in this article, where various types of inorganic layers (metal oxides, polynuclear transition metal cyanides, zeolites, metal porphyrins and phthalocyanines) are assessed.
References
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Electrochemistry of polynuclear transition metal cyanides: Prussian blue and its analogues
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The crystal structure of Prussian Blue: Fe4[Fe(CN)6]3.xH2O
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Some Performance Characteristics of a Prussian Blue Battery
TL;DR: In this paper, the feasibility of a Prussian blue battery with two half-cells was investigated, and it was shown that two halfcells could be combined to make a PB battery which, in the uncharged state, would consist of PB as both anode and cathode.
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Ion flux during electrochemical charging of Prussian Blue films
B.J. Feldman,Owen R. Melroy +1 more
TL;DR: In this article, the mass changes upon electrochemical reduction and oxidation of Prussian Blue films in the nitrate salts of K +, Rb +, and Cs + at pH 4, were measured.
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Electrochemical polychromicity in iron hexacyanoferrate films, and a new film form of ferric ferricyanide
TL;DR: A detailed voltammetric and coulometric study of both the conditions for electrodeposition from ferric ferricyanide solution, of Prussian Blue film on Pt, and of potential sweeps of the deposited film in KCl solution alone is reported in this article.