Journal ArticleDOI
Actinide oxalates, solid state structures and applications
Francis Abraham,Bénédicte Arab-Chapelet,Murielle Rivenet,Christelle Tamain,Stéphane Grandjean +4 more
TLDR
In this paper, the crystal growth methods addressed to non-soluble actinide (III) and (IV) oxalates and to soluble actinyl oxalate are presented.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2014-05-01. It has received 109 citations till now. The article focuses on the topics: Actinide.read more
Citations
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The Renaissance of Non-Aqueous Uranium Chemistry
TL;DR: Prior to the year 2000, non-aqueous uranium chemistry mainly involved metallocene and classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and oxo derivatives.
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Oxalate production by fungi: significance in geomycology, biodeterioration and bioremediation
Geoffrey M. Gadd,Geoffrey M. Gadd,Jaleh Bahri-Esfahani,Jaleh Bahri-Esfahani,Qianwei Li,Young Joon Rhee,Zhan Wei,Marina Fomina,Marina Fomina,Xinjin Liang +9 more
TL;DR: The importance of oxalate in geomycology, biodeterioration, environmental biotechnology and bioremediation is discussed in this article, where salient information from environmental and applied research is drawn together to emphasize the importance of Oxalate.
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Structural chemistry of uranium phosphonates
TL;DR: In this article, a comprehensive account of the crystal structures of uranium phosphonates and the various building units (e.g., discrete monomers, polymeric units, infinite chains, and sheets) that result from the numerous coordination modes of phosphonate ligands with uranium is presented.
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An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application
TL;DR: In this paper, the modularity, topology, and porosity of actinide metal-organic frameworks (An-MOFs) are specified to highlight a great potential to tune their electronic structures and ensuing properties.
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Low temperature decomposition of U(IV) and Th(IV) oxalates to nanograined oxide powders
Vaclav Tyrpekl,Jean-François Vigier,Dario Manara,Thierry Wiss,Oliver Dieste Blanco,Joseph Somers +5 more
TL;DR: In this paper, a low temperature decomposition of Th(C2O4)2⋅2H2O and (N2H5)2U2(C 2O4 )5 ⋅nH 2O into nanograined ThO2 and UO2 powders, which will be used later as precursors for the generation of materials emulating the nuclear fuel high burn up structure (HBS) was investigated.
References
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Metal carboxylates with open architectures.
TL;DR: The synthesis, structure, and properties of various types of open-framework metal carboxylates are discussed, for example, cadmium oxalate host lattices that can accommodate extended alkali-metal halide structures.
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Chemical actinometry (IUPAC Technical Report)
TL;DR: The first version of the IUPAC technical report on chemical actinometers was published in Pure Appl Chem 61, 187-210 (1989) as mentioned in this paper, and since then some methods have been improved, procedures have been modified, and new substances have been proposed as chemical act-inometers.
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U6+ minerals and inorganic compounds: insights into an expanded structural hierarchy of crystal structures
TL;DR: In this article, 368 inorganic crystal structures that contain essential U6+ are considered (of which 89 are minerals) and arranged on the basis of the topological details of their structural units, which are formed by the polymerization of polyhedra containing higher-valence cations.
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Hydro(solvo)thermal in situ ligand syntheses
TL;DR: In situ ligand synthesis has become a powerful approach in crystal engineering of coordination complexes and in organic synthesis, and is becoming an alternative approach in the isolation of organic isomers.