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Showing papers in "Coordination Chemistry Reviews in 2021"


Journal ArticleDOI
TL;DR: This review covers progress in the mass production and formation of MOFs along with future applications that are not currently well known but have high potential for new areas of MOF commercialization.

210 citations


Journal ArticleDOI
TL;DR: In this article, the authors summarized and highlighted the application of isoreticular chemistry in MOF structure design, including microstructure design, pore size tailoring, secondary building unit modification, post-synthesis modification, and cooperative regulation.

179 citations


Journal ArticleDOI
TL;DR: The mixed-linker-based multivariate metal-organic frameworks are synthesized employing various systematic strategies which include Linker-Directed Vertex De-symmetrization, Random Mixed-Linker Distribution, covalent pre-and post-synthetic modification techniques, etc as discussed by the authors.

164 citations


Journal ArticleDOI
TL;DR: The flexible supercapacitors integrated into the textile are characterized by a simple production process, low cost, fast charge, discharge speed, and long cycle life as discussed by the authors, therefore it has superior performance and broad research prospects.

159 citations


Journal ArticleDOI
TL;DR: In this paper, a review of reactive oxygen species (ROS)-selective fluorescent and luminescent probes based on metal-coordinated systems is presented, where metal ions play key roles in the probes as an on-off redox switch for photoinduced quenching and as a reaction site with ROS, RNS or luminecenters.

145 citations


Journal ArticleDOI
TL;DR: In this article, a comprehensive review of portable electrochemical (bio) sensing methods for point-of-care and on-site detection of pesticides residues in fruits and vegetables is presented.

135 citations


Journal ArticleDOI
TL;DR: In this article, the authors provide a comprehensive review of MOF-on-MOF hybrid materials constructed by the conjugation of two or more MOFs units and their derivates.

135 citations


Journal ArticleDOI
TL;DR: In this article, the authors provide a review on heterojunction catalysts in electrocatalytic water splitting, and discuss the catalytical mechanisms in HER and OER processes respectively.

135 citations


Journal ArticleDOI
TL;DR: Zhang et al. as mentioned in this paper summarized the current design and synthesis methods of ZIF-8 composites and provided new ideas for constructing high-efficient ZIF8 based adsorbent and photocatalyst.

130 citations


Journal ArticleDOI
TL;DR: In this article, the authors summarize the strategic evolution of directed C-H bond activation chemistry in this review and feel that this review would be of particular interest to scientists who are interested in progress made in the area of directed H-B bond functionalization, which could stimulate new areas of research regarding this significant topic.

129 citations


Journal ArticleDOI
TL;DR: This study provides a comprehensive overview of the major advances in colorimetric sensing approaches based on nanoparticle aggregation, label-free hydrogel particles, lateral flow immunoassays, integrated digital readers, portable field detection, and paper-based sensors for the on-site detection of pesticide residues in food crops.

Journal ArticleDOI
TL;DR: A review of multicarboxylate linkers in MOF systems and their applications, with specific emphasis on how high linker connectivity affects properties of MOFs such as topology, porosity, stability, and functionality can be found in this article.

Journal ArticleDOI
Zhao Li1, Ming Song1, Wenyou Zhu1, Wenchang Zhuang1, Xihua Du1, Lin Tian1 
TL;DR: In this paper, a comprehensive overview of compositional and structural properties of hollow heterostructure, which provides a large surface area, void spaces, and multiple interfaces for electrolytes/reactants impregnation, reduced diffusion lengths for mass transport, as well as structural strength for suppressing agglomeration, is presented.

Journal ArticleDOI
TL;DR: In this article, the most desirable properties of high-efficiency MOFs based adsorbents were revealed and the knowledge gaps were also scrutinized and future directions and perspectives for new experimental design.

Journal ArticleDOI
TL;DR: This review provides concise insights into the recent development of CDs in nanomedicine research, including preparation and functionalization processes, and a few critical applications are highlighted, such as antibacterial applications, chemotherapy, and therapeutics.

Journal ArticleDOI
TL;DR: In this paper, the authors summarized the latest research advances on universal strategies to synthesize multi-dimensional noble metal-based catalysts for electrocatalysis applications by structure optimizations, and concluded the classifications of various universal strategies on preparing MNMCs, involving universal hydro/solvothermal strategy, ligand-mediated method, template-assisted route, epitaxial growth, and CO-confinement strategy.

Journal ArticleDOI
TL;DR: This critical review of the design strategies, response mechanisms, and imaging applications of organic fluorescent probes for detection of polarity from 2010 to the present will facilitate the comprehension of superior fluorescent probe for polarity in the future.

Journal ArticleDOI
TL;DR: In this paper, the basic principles, material design, sensor performances, and worthwhile directions based on recently published works, focusing on five primary types of electrically-transduced gas sensors (chemiresistors, field effect transistors (FETs), electrochemical gas sensors, chemical diodes, and chemicapacitors).

Journal ArticleDOI
TL;DR: This review will provide a historical overview of the development and applications of porphyrin-based MOFs from early studies focused on design and structures, to recent efforts on their utilization in biomimetic catalysis, photocatalysis, electrocatalysis, sensing, and biomedical applications.

Journal ArticleDOI
TL;DR: This tutorial review summarizes the strategies for improving the efficacy of PDT in hypoxic tumor therapy, and demonstrates the advantages of combining PDT with other therapeutics, such as chemotherapy, chemo-dynamic therapy, gas therapy, immunotherapy and gene therapy.

Journal ArticleDOI
TL;DR: A brief introduction to the formation and physiological functions of LDs is provided in an attempt to highlight the importance of these underappreciated organelles and to create new LD fluorescent sensors that will further the understanding ofLDs and their associated physiology.

Journal ArticleDOI
TL;DR: A review of the sources, classification, fate and transport of emerging contaminants and the recent researches and advancements for their treatment/elimination will help in selecting the best available technology for specific contaminant under particular conditions.

Journal ArticleDOI
TL;DR: In this paper, the influence of MOF pore properties on the capture and separation of tailored guest molecules from the control of the supramolecular interactions for the first time.

Journal ArticleDOI
TL;DR: Based on the typical high-performance fluorophores, recent progress on molecularly NIR fluorescent probes for in vivo chemotherapy and phototherapy is highlighted with a particular focus on their design strategy and functionalization.

Journal ArticleDOI
TL;DR: Porphyrin and phthalocyanines are structurally related macrocyclic compounds with a highly conjugated π-electron system, which exhibit strong absorptions in the visible-light region and extraordinary thermal/chemical stability.

Journal ArticleDOI
TL;DR: This review summarizes the recent advances in CD-based fluorescent probes, including the design strategies, sensing mechanisms, and their applications in sensitive and selective detection of public safety substances, organic amines, phenols, bioactive molecules, biological enzymes, and inorganic salts.

Journal ArticleDOI
TL;DR: A comprehensive overview of metal-organic frameworks (MOFs)-based EC biosensors for detecting diverse targets (e.g., cancer markers, microRNA, and living cancer cells) that are considered as the indicators for early diagnosis of cancers is presented in this paper.

Journal ArticleDOI
TL;DR: This review highlighted the design principle and applications of fluorescent probes on the basis of the BODIPY skeleton since 2015, ranging from B ODIPY/aza-BODIPy small molecules and macromolecules to delicate nanoparticles for tracking of ROS/RNS and cancer imaging.

Journal ArticleDOI
TL;DR: In this article, a review of the recent progress made in the application of phthalocyanines as contrast agents for photothermal therapy (PTT) is presented, which not only discusses the molecular and/or supramolecular design considerations for enhancing the PTT effect of PH, but also provides the perspectives and challenges of the use of PH as contrast agent for PTT.

Journal ArticleDOI
TL;DR: An overview of the design principles of metal ion responsive AIEgens that can be generated using a modular approach can be found in this paper, where the authors have summarized the typical examples and their sensing mechanisms developed from 2005 to 2020.