Journal ArticleDOI
Adsorption of co on Pt(111) studied by photoemission, thermal desorption spectroscopy and high resolution dynamic measurements of work function
TLDR
The adsorption of CO on Pt(111) has been studied by XPS, UPS, thermal desorption mass spectroscopy and by dynamic and static work function measurements at 95, 298, 377,403 and 453 K as mentioned in this paper.About:
This article is published in Surface Science.The article was published on 1979-04-02. It has received 228 citations till now. The article focuses on the topics: Thermal desorption & Thermal desorption spectroscopy.read more
Citations
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Journal ArticleDOI
Core-level binding-energy shifts at surfaces and in solids
TL;DR: A review of core-level binding energy shifts observed in photoelectron spectroscopy can be found in this paper, where the authors focus on shifts since most of the chemical and physical insights provided by core levels are derived not from the core energies themselves but from shifts they exhibit.
Journal ArticleDOI
On the adsorption of CO on Pt(111)
TL;DR: In this article, the adsorption system Pt(111)-CO has been investigated with LEED, thermal desorption and vibrat on spectroscopy using electron energy losses (EELS).
Journal ArticleDOI
Alkali-metal-affected adsorption of molecules on metal surfaces
TL;DR: In this paper, a short review of the adsorption of alkali metals on well-defined transition metal surfaces is given and several models of the coadsorbed alkali metal-molecule complex are introduced.
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The adsorption of CO on Pt(111) studied by infrared reflection—Absortion spectroscopy
TL;DR: In this article, the interaction between CO and a clean Pt(111) surface at adsorption temperatures between 85 and 300 K has been studied with infrared reflection-absorption spectroscpy (IRAS) as well as with TPD and LEED.
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Vibrational Stark effect of adsorbates at electrochemical interfaces
TL;DR: In this article, the effect of cation size on (d ν d φ ) is explained by the vibrational Stark effect, which is explained in terms of CO's bonding.
References
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Book
Advanced Inorganic Chemistry
TL;DR: Cotton and Wilkinson's Advanced Inorganic Chemistry (AIC) as discussed by the authors is one of the most widely used inorganic chemistry books and has been used for more than a quarter century.
Journal ArticleDOI
Thermal desorption of gases
TL;DR: In this paper, the activation energy, rate constant and order of reaction from flash-filament desorption experiments were examined, and two heating schedules were considered: a linear variation of sample temperature with time (T = T 0+st), and a reciprocal temperature variation (1 T = 1 T 0 −αt).
Journal ArticleDOI
Chemisorption of CO on the Pt(111) surface
TL;DR: The work function at first decreases, exhibits a (temperature-dependent) minimum at θ = 13, attains nearly the value of the clean surface at 12 and again exhibits a second (shallow) minimum around 0.68 as mentioned in this paper.
Journal ArticleDOI
Synchrotron radiation study of chemisorptive bonding of CO on transition metals — Polarization effect on Ir(100)☆
TL;DR: In this paper, it was shown that the separation in energy between the 4σ and 1π peaks of chemisorbed CO varies systematically with the position of the adsorbent in the Periodic Table.
Journal ArticleDOI
Infrared spectra for co isotopes chemisorbed on Pt “111”: Evidence for strong absorbate coupling interactions
Alison Crossley,David A. King +1 more
TL;DR: In this paper, the vibrational spectra from a variety of mixtures of 12C16O and C16O were investigated and it was shown that there is a strong dipole-dipole coupling interaction between adsorbate molecules in the overlayer, and conclusive evidence that the 35 cm−1 frequency shift observed with increasing coverage for 12C 16O is attributable to coupling.
Related Papers (5)
Adsorption of CO on Pt(111) and Pt 6(111) × (111) studied by high resolution electron energy loss spectroscopy and thermal desorption spectroscopy
H. Hopster,H. Ibach +1 more