Journal ArticleDOI
Adsorption of phospholipids at the interface between two immiscible electrolyte solutions: Part I. Equilibrium adsorption of phosphatidylcholines at the water/nitrobenzene interface
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TLDR
In this article, an impedance technique was used to study the adsorption of 1,2-dilauroyl- (DLPC), 1, 2-dimyristoyl-(DMPC) and 1 2-dipalmitoylphosphatidylcholine (DPPC) at the interface between 0.05 M LiCl in water and 0.5 M tetrabutylammonium tetraphenylborate in nitrobenzene.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1988-02-25. It has received 40 citations till now. The article focuses on the topics: Adsorption & Nitrobenzene.read more
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Electrochemistry at the interface between two immiscible electrolyte solutions
TL;DR: In this article, the authors reviewed recent advances in the electrochemistry at the interface between two immiscible electrolyte solutions (ITIES) and discussed the polarizability of ITIES, ion transfer across the interface, facilitated transfer of ions, adsorption at the oil/water interface, electron transfer and applications to ion-selective electrodes, solvent extraction and membrane phenomena.
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Phospholipids at the Interface: Current Trends and Challenges
TL;DR: The properties of phospholipids at the air/water and oil/water interfaces, as well as the recent advances in using these natural components as stabilizers, alone or in combination with other compounds such as proteins are reviewed.
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Long-range electron transfer through a lipid monolayer at the liquid/liquid interface
TL;DR: The electron transfer rate at the interface between two immiscible electrolyte solutions was probed as a function of the driving force and distance between redox centers by scanning electrochemical microscopy as discussed by the authors.
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Electrical double layers at the oil/water interface
TL;DR: This review presents the historical development and current status of the theory of the electrical double layer at a liquid/liquid interface and gives rigorous thermodynamic definitions of all basic concepts related to liquid interfaces and to the Electrical double layer.
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Electrochemical determination of partition coefficients of drugs
Kyösti Kontturi,Lasse Murtomäki +1 more
TL;DR: An electrochemical method for the determination of partition coefficients of drugs that can exist as ions in aqueous solutions is presented and 1,2-dichloroethane, which has electronic properties similar to those of n-octanol, was used in the measurements.
References
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Reconstitution of Cell Membrane Structure in vitro and its Transformation into an Excitable System
TL;DR: By forming such a membrane between two compartments filled with saline its transverse electrical properties can be measured, and controlled chemical investigations can be undertaken.
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Electrolysis with electrolyte dropping electrode: II. Basic properties of the system
TL;DR: In this article, the basic equations for current-electrical potential difference across the interface have been deduced for the cases of ion as well as electron transfer for various base electrolyte systems.
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The double layer and ion adsorption at the interface between two non miscible solutions
TL;DR: In this article, the double layer was extended to the interface between two immiscible solutions and the model was composed of an inner compact layer, characterized by a dipolar potential drop, between two diffuse type layers.
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Double layers at liquid/liquid interfaces
TL;DR: In this article, the electrical double layer at the interface between two immiscible electrolyte solutions (ITIES) has been studied by the fast-galvanostatic-pulse method for the system consisting of aqueous NaBr and a solution of tetrabutylammonium tetraphenylborate in nitrobenzene.
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Theory of the kinetics of ion transfer across liquid/liquid interfaces
TL;DR: In this paper, a new formalism for the analysis of the kinetics of ion transfer across a polarised liquid/liquid interface is presented, based on the activated migration and diffusion transport models for homogeneous media.