Journal ArticleDOI
Analytical Applications of Matrix Isolation Fourier Transform Infrared Spectroscopy
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TLDR
A review of analytical applications of matrix isolation Fourier transform infrared spectroscopy is presented in this paper, along with practical techniques for obtaining analytically useful results, and a few studies relating to matrix isolation used in conjunction with Raman and conventional IR Spectroscopy are reviewed.Abstract:
A review of analytical applications of matrix isolation Fourier transform infrared spectroscopy is presented. The characteristics of matrix isolation spectroscopy are discussed along with practical techniques for obtaining analytically useful results. A few studies relating to matrix isolation used in conjunction with Raman and conventional IR spectroscopy are reviewed. The majority of analytical applications of matrix isolation vibrational spectroscopy has entailed the use of FT-IR techniques. Qualitative and quantitative results from a number of sample types are presented. The coupling of matrix isolation vibrational spectroscopy with chromatographic separations is reviewed.read more
Citations
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Journal ArticleDOI
High-resolution gas chromatography/matrix isolation infrared spectrometry
TL;DR: In this paper, an apparatus for the collection, within a matrix of condensed inert gas, of the effluent compounds from a high-resolution gas chromatograph is described, where each collected compound is contained within an area typically 0.3 mm in diameter yielding a concomitant high level of infrared spectral absorbance per nanogram of sample.
Journal ArticleDOI
Matrix-isolation infrared spectroscopy of organic phosphates
TL;DR: In this paper, the infrared spectra of trimethyl phosphate (TMP), triethyl phosphate and tri-n-butyl phosphate were obtained for argon and nitrogen matrices, and the peak widths of the sharpest features in matrix-isolated spectra were typically 2 cm-1.
Journal ArticleDOI
Structure and vibrational spectra of mononitrated benzo[a]pyrenes.
TL;DR: Detailed infrared and Raman spectroscopic data of BaP and its three mononitrated isomers are provided for the first time and structure-function relationships related to the mutagenicity of this important class of polycyclic aromatic hydrocarbons are discussed.
Journal ArticleDOI
Detection of mass 16 241 ions by Fourier-transform mass spectrometry.
I. J. Amster,Fred W. McLafferty,Miguel E. Castro,D. H. Russell,Robert B. Cody,Sahba. Ghaderi +5 more
TL;DR: In this paper, an independent investigation of the mass range of FTMS (Fourier-Transform mass spectroscopy) utilizing Cs DI to measure positive and negative cesium iodide cluster ions of masses as high as 16241 daltons was reported.
References
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Journal ArticleDOI
Matrix Isolation Method for the Experimental Study of Unstable Species
Journal ArticleDOI
Triple quadrupole mass spectrometry for direct mixture analysis and structure elucidation.
Richard A. Yost,Christie G. Enke +1 more
TL;DR: The triple quadrupole mass spectrometer is shown to be a simple and highly efficient system for the observation of the fragmentation pattern of selected ions that is virtually eliminated by the selection of both parent and fragment ion.
Book
Fourier Transform Infrared Spectroscopy: Applications to Chemical Systems
John R. Ferraro,Louis J. Basile +1 more
TL;DR: A survey of infrared data processing techniques can be found in this paper, where the authors present a survey of the state-of-the-art techniques in infrared spectroscopy, including Fourier Transform Infrared Reflection*b1Absorption Spectroscopy.