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Application of clay catalysts in organic synthesis. a review

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TLDR
In this article, the application of clay catalyssts in ORGANIC SYNTHESIS is discussed. And a review of the application can be found in the Appendix.
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This article is published in Organic Preparations and Procedures International.The article was published on 2008-02-01. It has received 66 citations till now. The article focuses on the topics: Organic synthesis.

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The Green ChemisTREE: 20 years after taking root with the 12 principles

TL;DR: The Green ChemisTrees as discussed by the authors is a showcase for the diversity of research and achievements stemming from green chemistry, inspired by tree diagrams that illustrate diversity of products stemming from raw materials.
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Environmentally benign synthesis of heterocyclic compounds by combined microwave-assisted heterogeneous catalytic approaches†

TL;DR: In this article, the application of heterogeneous catalysis combined with microwave irradiation in the synthesis of heterocyclic compounds is reviewed and the authors highlight the environmentally benign and sustainable nature of the combined microwave-assisted heterogeneous catalytic methods, highlighting the green aspects of individual synthetic approaches.
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Organic synthesis using clay and clay-supported catalysts

TL;DR: Clays and modified clays are used to catalyze various types of organic reactions such as addition, Michael addition, carbene addition and insertion, hydrogenation, alkylation, acylation, pericyclic reactions, condensation reactions, aldol formation, imine synthesis, diazotization reactions, synthesis of heterocycles, esterification reactions, rearrangement/isomerization reactions as discussed by the authors.
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Membranes from nanoporous 1D and 2D materials: A review of opportunities, developments, and challenges

TL;DR: In this article, the authors provide a comprehensive review of nanoporous 1D and 2D materials and discuss the applications of such materials in areas relating to molecular transport and separation, e.g. gas and liquid-phase separations, water purification, and ion-conducting membranes.
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Microwave-assisted multicomponent domino cyclization–aromatization: an efficient approach for the synthesis of substituted quinolines

TL;DR: In this article, a solid acid-catalyzed microwave-assisted synthesis of substituted quinolines is described, where the quinoline was synthesized by a multicomponent domino reaction of anilines, aldehydes and terminal aryl alkynes.
References
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Friedel–Crafts sulfonylation of aromatics catalysed by solid acids: An eco-friendly route for sulfone synthesis

TL;DR: In this paper, a mild and efficient catalytic method for Friedel-Crafts sulfonylation of arenes to the corresponding sulfones using a catalytic amount of reusable solid acid and arene- or alkanesulfonyl chlorides, sulfonic anhydrides and sulfonic acids as sulfonylating agents is described.
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Clay catalyzed conversion of isatoic anhydride to 2-(o-aminophenyl)oxazolines

TL;DR: A simple and environmentally safe procedure for the preparation of 2-(o-aminophenyl)oxazolines from isatoic anhydride is presented in this article, where a series of chiral derivatives of the title compound is prepared in moderate yield via natural kaolinitic clay catalyzed reactions with optically pure 2-aminoalcohols.
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Trialkylamine Controlled Phenol–Formaldehyde Reaction over Clay Catalysts: Selective and Environmentally Benign Synthesis of Salicylic Aldehydes

TL;DR: In this paper, Salicylic aldehydes were synthesized in good yields and excellent selectivities by reaction of phenols 1 with formaldehyde 2 over montmorillonite KSF-Et3N as a heterogeneous and reusable catalyst.
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K10 montmorillonite catalysis. C-C Bond formation by catalyzed conjugate addition and alkoxyalkylation of 1,3-dicarbonyl compounds

TL;DR: The intrinsic catalytic properties of K10 and KSF montmorillonites allow the achievement of more environmentally acceptable procedures for C-C bond formation: Michael addition and α-alkoxyalkylation of 1,3-dicarbonyl compounds as mentioned in this paper.
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Montmorillonite K-10 catalyzed synthesis of β-keto esters: condensation of ethyl diazoacetate with aldehydes under mild conditions

TL;DR: In this paper, a simple and efficient synthesis of β-keto esters using Montmorillonite K-10 catalyzed condensation of ethyl diazoacetate with various aldehydes at room temperature is described.
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