Journal ArticleDOI
Association of an acetylene with three metal atoms; new trinuclear cobalt complex. [Co atoms form 3-membered ring with 3 carbonyl groups bond to each Co atom]
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This article is published in Journal of the American Chemical Society.The article was published on 1958-12-20. It has received 77 citations till now. The article focuses on the topics: Ring (chemistry) & Cobalt.read more
Citations
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Book ChapterDOI
Compounds Derived from Alkynes and Carbonyl Complexes of Cobalt
R.S. Dickson,P.J. Fraser +1 more
TL;DR: In this article, the development of metal carbonyl chemistry is discussed and the rate of exchange of carbon monoxide with several other CO2(CO)6(RC2R´) complexes in hexane is investigated.
Journal ArticleDOI
Über Organometall‐Komplexe, VIII. Reaktionen von Kobaltcarbonyl‐Verbindungen mit Alkinen
Ulrich Krüerke,Walter Hübel +1 more
TL;DR: In this paper, a new Organo-Kobalt carbonyl-Komplexe were dargestellt, deren Strukturen sich durch Abbaureaktionen weitgehend aufklaren lieen.
Journal ArticleDOI
Uses of cobalt-carbonyl acetylene complexes in organic synthesis*†
P. L. Pauson,I. U. Khand +1 more
TL;DR: The most extensive information in the literature relates to iron carbonyls, from which a range of complexes have been obtained, the organic ligand of which is rarely the unchanged acetylene but, rather, is usually composed of one to three acetylene units with or without incorporation of one or two carbonyl groups as mentioned in this paper.
Journal ArticleDOI
Tricobalt carbon, an organometallic cluster
Book ChapterDOI
Chemistry of Carbon-Functional Alkylidynetricobalt Nonacarbonyl Cluster Complexes*
TL;DR: In this article, the chemistry of carbon-functional alkylidynetricobalt nonacarbonyl complexes is discussed, and the sensitivity of these compounds to diverse bases, nucleophiles, and oxidizing agents is discussed.
References
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Journal ArticleDOI
Polynuclear Metal Carbonyls. I. Structures of Mn2(CO)10 and Re2(CO)10
Journal ArticleDOI
Über Metallcarbonyle. 75. Von W. HIEBER und Mitarbeitern. Dipolmomente von Metallcarbonylverbindungen
TL;DR: In this paper, the authors show, das die Metall-CO-Bindung praktisch unpolar ist; ihr gegenuber weist MeNO in Metall-nitrosyl carbonylen ein nur um etwa 0,5 D verschiedenes Moment auf.
Journal ArticleDOI
Perchloryl fluoride, ClO3F: Preparation and some physical and chemical properties☆
Alfred Engelbrecht,H. Atzwanger +1 more
TL;DR: Perchloryl fluoride ClO3F has been prepared by electrolysis of a solution of sodium perchlorate in anhydrous hydrogen fluoride, and by reaction of potassium chlorate with elemental fluorine as mentioned in this paper.
Journal ArticleDOI
Polynuclear Metal Carbonyls. II. Structure of Iron Tetracarbonyl by X‐Ray Diffraction
Lawrence F. Dahl,R. E. Rundle +1 more
Related Papers (5)
The Molecular Structure of Co3(CO)9CCH3. A Tricyclic Organocobalt Complex Containing a Metal-Coordinated Triply Bridging Aliphatic Carbon Atom
Paul W. Sutton,Lawrence F. Dahl +1 more