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Attack of alkoxide ions on antimony in tetraarylstibonium salts

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This article is published in Journal of the American Chemical Society.The article was published on 1969-12-01. It has received 35 citations till now. The article focuses on the topics: Antimony & Alkoxide.

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Journal ArticleDOI

Synthesis, characterization and in vitro antitumor activity of some arylantimony ferrocenecarboxylates and crystal structures of C5H5FeC5H4CO2SbPh4 and (C5H5FeC5H4CO2)2Sb(4-CH3C6H4)3

TL;DR: Arylantimony ferrocenecarboxylates with the formula (C 5H 5 FeC 5 H 4 CO 2 ) n SbAr (5-n) (n = 1, 2; Ar = C 6H 5, 4-CH 3 C 6 H 4, 3CH 3C 6H 4, 2-CH3C 6h 4, 4-ClC 6 h 4, 4FC 6 h4 ) were synthesized and characterized by elemental analysis, IR, 1 H NMR and mass spectra.
Journal ArticleDOI

Synthesis, characterization and antitumor activity of some arylantimony triphenylgermanylpropionates and crystal structures of Ph3GeCH(Ph)CH2CO2SbPh4 and [Ph3GeCH2CH(CH3)CO2]2Sb(4-ClC6H4)3

TL;DR: Arylantimony(V) triphenylgermanylpropionates with the formula (Ph 3 GeCHR 1 CHR 2 CO 2 ) n SbAr (5− n ) (R 1 =H, Ph; R 2 =H and CH 3 ; n =1, 2) were synthesized and characterized by elemental analysis, IR, 1 H-NMR, 13 C-NMRI and mass spectroscopy as mentioned in this paper.
Journal ArticleDOI

Synthesis, crystal structures and in vitro antitumor activities of some organoantimony arylhydroxamates

TL;DR: A series of novel organoantimony arylhydroxamates with the formulae [Ar 3 SbL 2 ] − [HNEt 3 ] + (LH ǫ =arylhydroxamic acid; Ar à = C 6 H 5, 4-CH 3 C 6H 4, 3-CH CH 3 C 4 6 H 4, 4-ClC 6 H4,4-FC 6 h 4 ) and (4-CH 4 C 4 ) 4 SbLSbL were synthesized and characterized by elemental analysis
Journal ArticleDOI

Phosphonium-stibonium and bis-stibonium cations as pnictogen-bonding catalysts for the transfer hydrogenation of quinolines.

TL;DR: It is shown that antimony cations are generally more active than their phosphorus counterparts and neutral stiboranes and that dicationic systems such as [6]2+ are superior activators.
Journal ArticleDOI

Synthesis and in vitro antitumor activity of some tetraphenylantimony derivatives of exo-7-oxa-bicyclo[2,2,1]heptane(ene)-3-arylamide-2-acid

TL;DR: A series of tetraphenylantimony derivatives of exo-7-oxa-bicyclo[2,2,1] heptane (ene)-3-arylamide-2-acid of the general formula Ph 4 SbO 2 CCHCHCH 2 CH 2 CH(O)CHCONHAr (Ar = Ph,4-ClC 6 H 4, 4-BrC 6H 4, 3-Brc 6 H4, 4-F-3-clC 6 h 3 and 4-MeC 6h
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