Autocatalytic electroless nickel-boron plating on light alloys

TLDR: In this paper, the authors examined the possibility of depositing a thick autocatalytic electroless Ni-B plating on aluminium alloys and proposed an alkaline bath containing sodium borohydride as the reducing agent.

Abstract: Light alloys are more and more widely used, notably in aeronautics and the car industry. To improve their superficial properties, they can be covered with a hard and wear resistant protective layer. In this article, we examine the possibility of depositing a thick autocatalytic electroless Ni–B plating on aluminium alloys. We propose an alkaline bath containing sodium borohydride as the reducing agent. The deposition rate is held constant by a regular replenishment of the Ni–B bath allowing a rate of about 25 μm/h. The Knoop microhardness of the Ni–B deposits after the bath reaches about 750 hk100. Appropriate heat treatment can increase the deposit microhardness up to more than 1000 hk100 but must be applied with regard to the substrate properties. The study of these heat treatments will be published in a further paper.