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Carbenic reactivity revisited
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This article is published in Accounts of Chemical Research.The article was published on 1989-01-01. It has received 196 citations till now. The article focuses on the topics: Reactivity (chemistry).read more
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Looking for Stable Carbenes: The Difficulty in Starting Anew
TL;DR: The quest for stable carbenes is a long saga whose origin can be traced back to the first half of the 1800s as discussed by the authors, and the first stable crystalline carbene was reported in the early 1970s.
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A Brief Survey of Our Contribution to Stable Carbene Chemistry
TL;DR: This personal account summarizes the work, beginning with the discovery of the first stable carbene in 1988 up until the recent isolation of mesoionic carbenes, showing that these stable species are not limited to the role of ligand for transition metals, but that they are also powerful agents for the activation of small molecules, and for the stabilization of highly reactive diamagnetic and paramagnetic species.
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Formal [4+1] Annulation Reactions in the Synthesis of Carbocyclic and Heterocyclic Systems
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The Addition of Dichlorocarbene to Olefins
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The Halogenation of Amidines. I. Synthesis of 3-Halo- and Other Negatively Substituted Diazirines1
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"Anhydrous" tetrabutylammonium fluoride: a mild but highly efficient source of nucleophilic fluoride ion
TL;DR: Etude de la reactivite du fluorure de tetrabutylammonium avec une serie de composes organiques substitues par un halogene ou un groupe tosyl (contenant un carbone: allylique, benzylique and primaire, secondaire and tertiaire sp 3 ou sp 2 active) as mentioned in this paper.