Journal ArticleDOI
Carbonyl-η5-cyclopentadienyl(1,1,4,7,7-pentaphenyl-1,4,7-triphosphaheptane)vanadium(I), η5-C5H5V(CO)PPh(CH2CH2PPH2)2
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TLDR
The molecular structure and spectroscopic properties of the title compound are reported in this article, where the vanadium atom is centered between the two best planes spanned by the cyclopentadienyl ring and the three phosphorus atoms plus the CO ligand.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1981-06-30. It has received 15 citations till now. The article focuses on the topics: Cyclopentadienyl complex & Vanadium.read more
Citations
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Journal ArticleDOI
Preparation and Characterization of Mono-cyclopentadienylvanadium Dihalide Bis-phosphine Complexes; Crystal Structure of (η5-C5H5)VCl2(PMe3)2
TL;DR: In this paper, the crystal structure of the trimethylphosphine complex CpVCl 2 (PMe 3 ) 2 is reported, and the reduction of PMe 3 with zinc or aluminium under CO (1 bar) offers a simple method for the preparation of PV(CO) 3 (PEt 3 ).
Journal ArticleDOI
Carbonylvanadium‐Halbsandwichkomplexe: Darstellung, Struktur und 51V‐NMR‐Spektren von Derivaten des μ5‐C5H5V(CO)4
Martin Hoch,Dieter Rehder +1 more
TL;DR: In this article, a number of Halbsandwichkomplexes have been investigated, e.g., Cp′V(CO)4I (offene Cp-Derivate) and III (anellierte CpDerivates) darstellbar.
Journal ArticleDOI
The coordinative properties of the ligands Ph2ECH2EPh2 (E = P, As, Sb) in carbonylvanadium complexes, and the molecular structure of η5-C5H5V(CO)3As2Ph4
TL;DR: The vanadium compound η5-C5H5V(CO)3As2Ph4 has been determined in this paper, and its crystal and molecular structures have been determined.
References
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Journal ArticleDOI
Crystal and molecular structures of dichloro[bis(diphenylphosphino)methane]palladium(II), dichloro[bis(diphenylphosphino)ethane]palladium(II), and dichloro[1,3-bis(diphenylphosphino)propane]palladium(II)
W. L. Steffen,Gus J. Palenik +1 more
Journal ArticleDOI
Klassifizierung phosphorhaltiger Liganden in Metallcarbonyl-Derivaten nach der π-Acceptorstärke
TL;DR: The π-Acceptor starke am Phosphoratom der Liganden bestimmt is unabhangig vom jeweiligen Metallatom des Metallcarbonyls and kann klassifiziert werden, wobei typische Verbindungen als Vertreter der Klassen gewahlt wurden as mentioned in this paper.
Journal ArticleDOI
Unsymmetrical bis-phosphorus ligands. IV. Group VI metal carbonyl derivatives of diphenylphosphinomethyl and diphenylphosphinomethyl phosphinites, (C6H5)2P(CH2)nOP(C6H5)2, n = 1 or 2, and an unusual phosphorus chemical shift chelate effect
Related Papers (5)
Steric and electronic effects on 31P and 51V shielding in carbonylphosphinevanadium complexes
cis-dicarbonyl-η5-cyclopentadienyl -1,1,4,4-tetraphenyl-1,4-diphosphabutane-vanadium(+I)cis-[η5-CpV(CO)2{Ph2P(CH2)2PPh2}]
Synthesis and nmr-spectroscopy characteristics of carbonylhydridovanadium complexes stabilized by oligotertiary phosphines
Uwe Puttfarcken,Dieter Rehder +1 more