Journal ArticleDOI
Catalysis of the diels-alder reaction
G.I. Fray,Robert J. Robinson +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1961-01-01. It has received 83 citations till now. The article focuses on the topics: Homogeneous catalysis & Hydrogen bond catalysis.read more
Citations
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Journal ArticleDOI
Application of commercial microwave ovens to organic synthesis.
TL;DR: In this article, commercial microwave ovens have been safely used to dramatically reduce the reaction times (at comparable yield) of Diels-Alder, Claisen, and ene reactions.
Journal ArticleDOI
Diels‐Alder‐Reaktionen: Zum Reaktionsmechanismus
TL;DR: In this paper, the mechanistischen Alternativen der praparativ so fruchtbaren Diels-Alder-Reaktionen anhand der experimentellen Fakten kritisch zu diskutieren.
Journal ArticleDOI
Design of Brønsted Acid-Assisted Chiral Lewis Acid (BLA) Catalysts for Highly Enantioselective Diels−Alder Reactions
TL;DR: In particular, excellent enantioselectivity was achieved due to intramolecular hydrogen bonding interaction and attractive π−π donor−acceptor interaction in the transition-state assembly by hydroxy aromatic groups in a chiral BLA catalyst as mentioned in this paper.
Journal ArticleDOI
Ring expansion of cyclobutylmethylcarbenium ions to cyclopentane or cyclopentene derivatives and metal-promoted analogous rearrangements.
Journal ArticleDOI
Partial asymmetric synthesis in the diels-alder reaction☆
TL;DR: In this article, the Diels-Alder condensation of (−)-dimenthyl fumarate with butadiene followed by reduction of the adduct with LiAlH 4, produced (−)-(1R:2R)-4-cyclohexene- trans -1,2-dimethanol in 1 − 3% optical purity depending on the temperature used to carry out the reaction.
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