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Journal ArticleDOI

Catalysis of the diels-alder reaction

G.I. Fray, +1 more
- 01 Jan 1961 - 
- Vol. 83, Iss: 1, pp 249-249
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This article is published in Journal of the American Chemical Society.The article was published on 1961-01-01. It has received 83 citations till now. The article focuses on the topics: Homogeneous catalysis & Hydrogen bond catalysis.

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Journal ArticleDOI

Application of commercial microwave ovens to organic synthesis.

TL;DR: In this article, commercial microwave ovens have been safely used to dramatically reduce the reaction times (at comparable yield) of Diels-Alder, Claisen, and ene reactions.
Journal ArticleDOI

Diels‐Alder‐Reaktionen: Zum Reaktionsmechanismus

TL;DR: In this paper, the mechanistischen Alternativen der praparativ so fruchtbaren Diels-Alder-Reaktionen anhand der experimentellen Fakten kritisch zu diskutieren.
Journal ArticleDOI

Design of Brønsted Acid-Assisted Chiral Lewis Acid (BLA) Catalysts for Highly Enantioselective Diels−Alder Reactions

TL;DR: In particular, excellent enantioselectivity was achieved due to intramolecular hydrogen bonding interaction and attractive π−π donor−acceptor interaction in the transition-state assembly by hydroxy aromatic groups in a chiral BLA catalyst as mentioned in this paper.
Journal ArticleDOI

Partial asymmetric synthesis in the diels-alder reaction☆

TL;DR: In this article, the Diels-Alder condensation of (−)-dimenthyl fumarate with butadiene followed by reduction of the adduct with LiAlH 4, produced (−)-(1R:2R)-4-cyclohexene- trans -1,2-dimethanol in 1 − 3% optical purity depending on the temperature used to carry out the reaction.