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Chapter 12 – Laser-Induced Breakdown Spectroscopy: Advanced Analytical Technique

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TLDR
Laser induced breakdown spectroscopy (LIBS) as discussed by the authors is a technique where atoms and ions are primarily formed in their excited states as a result of interaction between a tightly focused laser beam and the material sample.
Abstract
Laser induced breakdown spectroscopy (LIBS) is basically an emission spectroscopy technique where atoms and ions are primarily formed in their excited states as a result of interaction between a tightly focused laser beam and the material sample. The interaction between matter and high-density photons generates a plasma plume, which evolves with time and may eventually acquire thermodynamic equilibrium. One of the important features of this technique is that it does not require any sample preparation, unlike conventional spectroscopic analytical techniques. Samples in the form of solids, liquids, gels, gases, plasmas and biological materials (like teeth, leaf or blood) can be studied with almost equal ease.LIBS has rapidly developed into a major analytical technology with the capability of detecting all chemical elements in a sample, of real- time response, and of close-contact or stand-off analysis of targets. The present book has been written by active specialists in this field, it includes the basic principles, the latest developments in instrumentation and the applications of LIBS. It will be useful to analytical chemists and spectroscopists as an important source of information and also to graduate students and researchers engaged in the fields of combustion, environmental science, and planetary and space exploration. It features: recent research work, possible future applications and LIBS Principles.

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Citations
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Journal ArticleDOI

Quantification of copper remediation in the Allium cepa L. leaves using electric field assisted laser induced breakdown spectroscopy

TL;DR: In this paper, trace constituents of three plants of Onion (Allium cepa L), grown in the prepared soil containing varying concentration of copper under controlled environment to check its remediation capacity using LIBS.
Journal ArticleDOI

Ablation and Spectroscopic Characteristics of Thin CuIn1-xGaxSe2 Solar Cell Films Fabricated by Co- Evaporation and Co-Sputtering Processes

TL;DR: In this paper, the influence of fabrication processes on the LIBS spectra of major and minor chemical constituents in CIGS absorber films produced by co-sputtering and co-evaporation techniques on Mo-coated soda lime glass (SLG) is reported.
Journal ArticleDOI

Feasibility Study on Discrimination of Neo-plastic and Non-Neoplastic Gastric Tissues Using Spark Discharge Assisted Laser Induced Breakdown Spectroscopy.

TL;DR: The SD-LIBS technique had the potential to discriminate normal and cancerous tissues based on the significant differences in the intensities of some particular elements and could be viewed as a practical measure for tissue discrimination since Ca and Mg peaks in spectra of neoplastic were noticeably higher than nonneoplastic.
Journal ArticleDOI

Effect of Melting Iron-Based Alloy Temperature on Carbon Content Observed in Laser-Induced Breakdown Spectroscopy*

TL;DR: In this article, the authors compare the errors of carbon content determination at different temperatures to find the optimum reference temperature range which can fit the requirements better in industrial conditions and, hence, make the measurement more accurate.
Journal ArticleDOI

Transport of high-fluence energy by femtosecond filament in air

TL;DR: In this paper, the authors present a numerical investigation of high-fluence energy transport by femtosecond filament in air and show that an increase of the initial pulse duration leads to an increase in the energy in the pulse and to its higher localization in the filament.
References
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Book

Spectral Line Broadening by Plasmas

TL;DR: SpectSpectral Line Broadening by Plasmas as discussed by the authors provides a theoretical overview of the spectral line broadening mechanism and its application in the field of plasma spectroscopy, with a focus on spectral lines.
Book

Handbook of laser-induced breakdown spectroscopy

TL;DR: In this article, the authors present an overview of the current state of the art in the field of laser-induced breakdown spectroscopy (LIBS) and its application in various applications.
Book

Principles of Plasma Spectroscopy

TL;DR: The diagnosis of plasmas using spectroscopic observations has its origins in various older disciplines, including astronomy and discharge physics as mentioned in this paper, and the need for non-interfering diagnostics arose and spectroscopy was applied to determine the physical state and chemical abundance of the studied.
Journal ArticleDOI

Laser-induced breakdown spectroscopy.

TL;DR: Compared to the conventional flame emission spectroscopy, LIBS atomizes only the small portion of the sample by the focused laser pulse, which makes a tiny spark on the sample, and capturing the instant light is a major skill to collect sufficient intensity of the emitting species.
Journal ArticleDOI

Local Thermodynamic Equilibrium in Laser-Induced Breakdown Spectroscopy: Beyond the McWhirter criterion

TL;DR: In this article, the authors reviewed the theoretical analysis underlying the concept of thermodynamic equilibrium and the derivation of the McWhirter criterion, and critically discussed its application to a transient and nonhomogeneous plasma, like that created by a laser pulse on solid targets.