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Chapter 12 – Laser-Induced Breakdown Spectroscopy: Advanced Analytical Technique

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TLDR
Laser induced breakdown spectroscopy (LIBS) as discussed by the authors is a technique where atoms and ions are primarily formed in their excited states as a result of interaction between a tightly focused laser beam and the material sample.
Abstract
Laser induced breakdown spectroscopy (LIBS) is basically an emission spectroscopy technique where atoms and ions are primarily formed in their excited states as a result of interaction between a tightly focused laser beam and the material sample. The interaction between matter and high-density photons generates a plasma plume, which evolves with time and may eventually acquire thermodynamic equilibrium. One of the important features of this technique is that it does not require any sample preparation, unlike conventional spectroscopic analytical techniques. Samples in the form of solids, liquids, gels, gases, plasmas and biological materials (like teeth, leaf or blood) can be studied with almost equal ease.LIBS has rapidly developed into a major analytical technology with the capability of detecting all chemical elements in a sample, of real- time response, and of close-contact or stand-off analysis of targets. The present book has been written by active specialists in this field, it includes the basic principles, the latest developments in instrumentation and the applications of LIBS. It will be useful to analytical chemists and spectroscopists as an important source of information and also to graduate students and researchers engaged in the fields of combustion, environmental science, and planetary and space exploration. It features: recent research work, possible future applications and LIBS Principles.

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Citations
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Journal ArticleDOI

Investigation of multi-layered silicate ceramics using laser ablation optical emission spectrometry, laser ablation inductively coupled plasma mass spectrometry, and electron microprobe analysis

TL;DR: In this paper, the applicability of laser ablation (LA) inductively coupled plasma (ICP) spectrometry for assessing elemental distributions in layered ceramics was investigated and compared with electron probe microanalysis (EPMA).
Journal ArticleDOI

Spatial and temporal dynamics of a pulsed spark microplasma used for aerosol analysis

TL;DR: In this article, the spatial and temporal dynamics of a pulsed electrical spark microplasma used for spectrochemical analysis of aerosols was investigated, where the spark discharge was generated by applying a high voltage pulse between a coaxial anode and cathode.
Journal ArticleDOI

Elemental profiling of surface water around dhaka city by laser induced breakdown spectroscopy

TL;DR: Using the technique of Laser Induced Breakdown Spectroscopy (LIBS), which uses a pulsed laser to create plasma and advanced spectroscopic techniques, the authors analyzed the contents of surface water (river water) around the city of Dhaka.
Journal ArticleDOI

Validation of the solidifying soil process using laser-induced breakdown spectroscopy

TL;DR: In this article, laser-induced breakdown spectroscopy (LIBS) was used to detect the ion contents of K, Ca, Na, Mg, Al, and Si in the permeable fluid after the solidified soil samples have been permeated.
Journal ArticleDOI

Analysis of alloy and solar cells with double-pulse calibration-free laser-induced breakdown spectroscopy

TL;DR: In this paper, a variant of calibration free laser induced Breakdown Spectroscopy (CF-LIBS) approach was applied for compositional analysis of standard Gd/Ge/Si alloy and solar cells.
References
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Book

Spectral Line Broadening by Plasmas

TL;DR: SpectSpectral Line Broadening by Plasmas as discussed by the authors provides a theoretical overview of the spectral line broadening mechanism and its application in the field of plasma spectroscopy, with a focus on spectral lines.
Book

Handbook of laser-induced breakdown spectroscopy

TL;DR: In this article, the authors present an overview of the current state of the art in the field of laser-induced breakdown spectroscopy (LIBS) and its application in various applications.
Book

Principles of Plasma Spectroscopy

TL;DR: The diagnosis of plasmas using spectroscopic observations has its origins in various older disciplines, including astronomy and discharge physics as mentioned in this paper, and the need for non-interfering diagnostics arose and spectroscopy was applied to determine the physical state and chemical abundance of the studied.
Journal ArticleDOI

Laser-induced breakdown spectroscopy.

TL;DR: Compared to the conventional flame emission spectroscopy, LIBS atomizes only the small portion of the sample by the focused laser pulse, which makes a tiny spark on the sample, and capturing the instant light is a major skill to collect sufficient intensity of the emitting species.
Journal ArticleDOI

Local Thermodynamic Equilibrium in Laser-Induced Breakdown Spectroscopy: Beyond the McWhirter criterion

TL;DR: In this article, the authors reviewed the theoretical analysis underlying the concept of thermodynamic equilibrium and the derivation of the McWhirter criterion, and critically discussed its application to a transient and nonhomogeneous plasma, like that created by a laser pulse on solid targets.