Journal ArticleDOI
Charge transfer in mixed-valence solids. Part VIII. Contribution of valence delocalisation to the ferromagnetism of Prussian Blue
Bryan Mayoh,Peter Day +1 more
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The contribution of mixed-valence electron delocalisation to the ferromagnetic exchange between the iron(III) ions in Prussian Blue {FeIII4[eII(CN)6]3·14H2O} has been estimated theoretically.Abstract:
The contribution of mixed-valence electron delocalisation to the ferromagnetic exchange between the iron(III) ions in Prussian Blue {FeIII4[eII(CN)6]3·14H2O} has been estimated theoretically. Agreement between the calculated and observed values of the Curie temperature is quite good.read more
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Journal ArticleDOI
Old materials with new tricks: multifunctional open-framework materials.
TL;DR: This critical review provides an up-to-date survey to this new generation of multifunctional open-framework solids, classified into five different sections: magnetic, chiral, conducting, optical, and labile open-frameworks for sensing applications.
Journal ArticleDOI
Control of magnetic properties through external stimuli.
TL;DR: Most of the Review is devoted to the properties of valence-tautomeric compounds, molecular magnets, and spin-crossover complexes, which could find future application in memory devices or optical switches.
Book ChapterDOI
Chemistry of Transition Metal Cyanide Compounds: Modern Perspectives
Kim R. Dunbar,Robert A. Heintz +1 more
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Nickel(II)−Molybdenum(III)−Cyanide Clusters: Synthesis and Magnetic Behavior of Species Incorporating [(Me3tacn)Mo(CN)3]
TL;DR: The substitution of Mo(III) for Cr( III) in metal-cyanide clusters is demonstrated as an effective means of increasing the strength of the magnetic exchange coupling and introducing magnetic anisotropy.
Journal ArticleDOI
Cluster-Expanded Prussian Blue Analogues
TL;DR: In this paper, a method for expanding the pores in crystalline frameworks is demonstrated with the substitution of face-capped octahedral [Re6Q8(CN)6]4- (Q = Se, Te) clusters into the Prussian blue structure.