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Chemical origins of substituent effects in alkylpentacarbonylmanganese(I) group migration reactions
Frank U. Axe,Dennis S. Marynick +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1988-06-01. It has received 48 citations till now. The article focuses on the topics: Substituent & Isomerization.read more
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Theoretical studies on reactions of transition-metal complexes.
Shuqiang Niu,Michael B. Hall +1 more
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Coordination−Insertion Copolymerization of Fundamental Polar Monomers
TL;DR: Akifumi Nakamura’s research interests include synthetic organic chemistry, organometallic chemistry, computational chemistry, and polymer chemistry.
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Theoretical Studies of Some Transition-Metal-Mediated Reactions of Industrial and Synthetic Importance.
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Cationic Polymerization and Insertion Chemistry in the Reactions of Vinyl Ethers with (α-Diimine)PdMe+ Species
TL;DR: For 2d-g, the insertion chemistry out-competes cationic polymerization even at high vinyl ether concentrations, and beta-OR elimination of 4/5 mixtures is faster for SbF(6)(-) salts than B(C(6)F(5))(4)(+) salts.
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Reactions of vinyl acetate and vinyl trifluoroacetate with cationic diimine Pd(II) and Ni(II) alkyl complexes: identification of problems connected with copolymerizations of these monomers with ethylene.
TL;DR: These quantitative studies provide an explanation for the behavior of VA and VA(f) in attempted copolymerizations with ethylene.