Journal ArticleDOI
Chiral aluminum complexes as catalysts in asymmetric Baeyer-Villiger reactions of cyclobutanones
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BINOL-aluminum complexes were successfully employed as mediators and catalysts in asymmetric Baeyer-Villiger rearrangements of cyclobutanones.Abstract:
BINOL-aluminum complexes were successfully employed as mediators and catalysts in asymmetric Baeyer-Villiger rearrangements of cyclobutanones. Good enantioselectivies were achieved with only 15 mol...read more
Citations
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Efficiency in nonenzymatic kinetic resolution.
Edwin Vedejs,Mara Jure +1 more
TL;DR: The story of kinetic resolution from the early discoveries through fascinating historical milestones and conceptual developments is followed, and a focus on modern techniques that maximize efficiency is closed.
Journal ArticleDOI
Enantiomerically pure cyclobutane derivatives and their use in organic synthesis.
Journal ArticleDOI
Catalytic Asymmetric Synthesis of Butenolides and Butyrolactones
TL;DR: This review offers an overview of the different enantioselective synthesis of γ-butenolides andγ-butyrolactones which employ catalytic amounts of metal complexes or organocatalysts, with emphasis focused on the mechanistic issues that account for the observed stereocontrol of the representative reactions, as well as practical applications and synthetic potentials.
Journal ArticleDOI
Effizienz in der nichtenzymatischen kinetischen Racematspaltung
Edwin Vedejs,Mara Jure +1 more
TL;DR: The Walden-Denkmal as discussed by the authors is angefangen von den ersten Entdeckungen der tetraedrischen Natur des Kohlenstoffs.
References
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Journal ArticleDOI
Catalytic Enantioselective Ring-Closing Metathesis by a Chiral Biphen−Mo Complex
Journal ArticleDOI
Chiral mo-binol complexes : activity, synthesis, and structure. efficient enantioselective six-membered ring synthesis through catalytic metathesis
S. Sherry Zhu,Dustin R. Cefalo,Daniel S. La,Jennifer Y. Jamieson,William M. Davis,Amir H. Hoveyda,Richard R. Schrock +6 more
TL;DR: In this article, a new class of chiral Mo-based complexes 2a and 2b, bearing functionalized chiral binol ligands, is disclosed, which are particularly effective in the enantioselective synthesis of five-membered rings by ARCM.
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