Journal ArticleDOI
Competitive carbonylation pathways from a dialkyl A-frame complex
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This article is published in Journal of the American Chemical Society.The article was published on 1991-06-01. It has received 15 citations till now. The article focuses on the topics: Carbonylation & Reaction mechanism.read more
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Enzyme-catalyzed organic synthesis: practical routes to aza sugars and their analogs for use as glycoprocessing inhibitors
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“Short-bite” ligands in cluster synthesis
TL;DR: The short-bite ligands CH2(PR2)2 or CH(PR3)3 are particularly versatile for the synthesis of di-and polynuclear complexes which frequently possess metal-metal bonds as discussed by the authors.
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An ab initio study of facial selectivity in the Diels-Alder reaction
TL;DR: Facial selectivities in the Diels-Alder reactions of 5-substituted 1,3-cyclopentadienes with a variety of dienophiles are predicted reliably at the ab initio HF/6-31G level and the first definition of an abinitio steric factor is presented which correlates very well with syn activation energies.
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Reactivity of the Heterobinuclear Phenylacetylide-Bridged A-Frame [RhIr(CO)2(μ-CCPh)(Ph2PCH2PPh2)2][O3SCF3] with Small Molecules
TL;DR: The compound [RhIr(CO)2(μ-CCPh)(dppm)2][O3SCF3] (2, dppm = Ph2PCH2PPh2) is an A-frame species in which the bridging phenylacetylide group is σ-bound to iridium and functioning as a π donor to rhodium as discussed by the authors.
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Reductive elimination of alkanes and arenes from [Pd{sub 2}R{sub 2}({micro}-H)({micro}-dppm){sub 2}]PF{sub 6} complexes
TL;DR: In this article, a series of halide and hydride-bridged dipalladium A-frame cations of the type [Pd{sub 2}R{ sub 2}