Competitive photochlorination and kinetic isotope effects for hydrogen/deuterium abstraction from the methyl group in C2H6, C2D6, CH3CHCl2, CD3CHCl2, CH3CCl3, and CD3CCl3
TLDR
The abstraction of hydrogen and deuterium from ethane, 1,1-dichloroethane and 1, 1-trichloromethane by photochemically generated ground state chlorine atoms has been studied in this article.Abstract:
The abstraction of hydrogen and deuterium from ethane, 1,1-dichloroethane, 1,1,1-trichloroethane, and some of their deuterated analogs by photochemically generated ground state chlorine atoms has b...read more
Citations
More filters
Journal ArticleDOI
Measurements, theory, and modeling of OH formation in ethyl + O2 and propyl + O2 reactions
TL;DR: The time-resolved formation of OH from ethyl + O2 and propyl+ O2 reactions has been measured by OH laser-induced fluorescence in pulsed-photolytic Cl-initiated oxidation of ethane and propane between 296 and 700 K.
Journal ArticleDOI
Hydrogen Atom Transfer Reactions via Photoredox Catalyzed Chlorine Atom Generation
TL;DR: The mild, controlled, and catalytic generation of chlorine atoms are reported as a new opportunity for access to a wide variety of hydrogen atom transfer (HAT) reactions owing to the high stability of HCl.
Journal ArticleDOI
Rate Constants and Kinetic Isotope Effects in the Reactions of Atomic Chlorine with n-Butane and Simple Alkenes at Room Temperature
TL;DR: In this paper, the rate constants for the reactions of chlorine atoms with n-butane and simple alkenes, as well as most of their deuterated analogs, were studied at room temperature using two independent techniques.
Journal ArticleDOI
Differential cross section polarization moments: Location of the D-atom transfer in the transition-state region for the reactions Cl+C2D6→DCl(v′=0,J′=1)+C2D5 and Cl+CD4→DCl(v′=0,J′=1)+CD3
TL;DR: The photoloc technique can also be used to measure the polarization dependence for all moments of orientation and alignment with k⩽2 in the stationary target frame (STF) as discussed by the authors, which is defined by Aq(k)stf=(dσkqstf/dΩr)/(dσ00/d Ωr).
Journal ArticleDOI
Absolute and Site-Specific Abstraction Rate Coefficients for Reactions of Cl with CH3CH2OH, CH3CD2OH, and CD3CH2OH between 295 and 600 K
TL;DR: In this article, the absolute rate coefficients for reactions of Cl atoms with selectively deuterated ethanols have been measured between 295 and 600 K by a laser-photolysis/CW infrared absorption method.