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Journal ArticleDOI

Core and valence level photoemission studies of iron oxide surfaces and the oxidation of iron

C.R. Brundle, +2 more
- 01 Nov 1977 - 
- Vol. 68, pp 459-468
TLDR
The core and valence level XPS spectra of FexO (x ~ 0.90-0.95), Fe2O3 (α and γ), Fe3O4; and FeOOH have been studied under a variety of sample surface conditions as discussed by the authors.
About
This article is published in Surface Science.The article was published on 1977-11-01. It has received 577 citations till now. The article focuses on the topics: Valence (chemistry) & Iron oxide.

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Citations
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Journal ArticleDOI

Analysis of XPS spectra of Fe2+ and Fe3+ ions in oxide materials

TL;DR: In this paper, the peak positions and peak shape parameters of Fe 3p for Fe2+ and Fe3+ were derived from the XPS spectra of the standard samples of 2FeO·SiO2 and Fe2O3, respectively.
Journal ArticleDOI

A study of the core level electrons in iron and its three oxides by means of X-ray photoelectron spectroscopy

P Mills, +1 more
- 14 May 1983 - 
TL;DR: In this paper, the core level electrons in iron and its three oxides FeO, Fe3O4 and alpha -Fe2O3 have been studied by means of X-ray photoelectron spectroscopy.
Journal ArticleDOI

Photoemission studies of adsorbed oxygen and oxide layers

TL;DR: A comprehensive review about the versatility of photoelectron spectroscopy to study the especially complex interaction of oxygen with metal surfaces and the nature of the reaction products can be found in this paper.
Journal ArticleDOI

Nanostructured hematite: synthesis, characterization, charge carrier dynamics, and photoelectrochemical properties

TL;DR: In this article, the authors provide an overview of recent progress on the synthesis and characterization of nanostructured hematite, with an emphasis on the charge carrier dynamics and photoelectrochemical properties.
Journal ArticleDOI

The nature of the iron oxide-based catalyst for dehydrogenation of ethylbenzene to styrene 2. Surface chemistry of the active phase

TL;DR: In this paper, an XPS/UPS surface analysis instrument with a micro-reactor allowed the investigation of the surface composition of catalysts characterized by varying activities and selectivities.
References
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Journal ArticleDOI

Hartree-Slater subshell photoionization cross-sections at 1254 and 1487 eV.

TL;DR: In this article, the results of photoelectric cross-sections for the Kα lines of magnesium at 1254 eV and of aluminum at 1487 eV were given for Z values up to 96.
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Interpretation of the x-ray photoemission spectra of cobalt oxides and cobalt oxide surfaces

TL;DR: In this article, high-resolution X-ray photoemission of CoO and Co3O4 has been studied and the properties of the Co 2p 3 2, 2p 1 2, and 3s regions, their band shapes and widths, the associated shake-up structure, and the O(1s) and O(2s) BE's were examined.
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Calculation of multiplet structure of core p -vacancy levels. II

TL;DR: In this article, the multiplet splittings of core $p$-vacancy levels have been observed in various transition-metal complexes and in some rare-earth as well as actinide complexes.
Journal ArticleDOI

ESCA studies of metal-oxygen surfaces using argon and oxygen ion-bombardment

TL;DR: In this paper, a model based on bulk thermodynamic free energy considerations is proposed to explain the sputtering of metal-oxygen surfaces following exposure to Ar + and O 2 + ion bombardment.
Journal ArticleDOI

X-Ray photoelectron spectroscopy of iron–oxygen systems

TL;DR: In this article, it was shown that small perturbations to the energy of the iron (III) 2p electrons can be attributed to changes in crystal structure and multiplet splitting and shake-up in the iron oxides contributes to iron 2p peak widths; the chemisorption of water has a marked effect upon the observed peak profiles; the oxygen 1s peaks due to oxide, hydroxyl, and adsorbed water have been characterised.
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